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Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst
Wang, Ke-Feng1,2,4; Liu, Chun-lei3; Sui, Kun-yan1; Guo, Chen2; Liu, Chun-Zhao1,2
2018-04-04
Source PublicationCHEMBIOCHEM
ISSN1439-4227
Volume19Issue:7Pages:654-659
Abstract2,5-Furandicarboxylic acid (FDCA) is a bio-based platform chemical for the production of polyethylene furanoate (PEF) and other valuable furanic chemicals. A magnetic laccase catalyst with (2,2,6,6-tetramethyl-piperidin-1-yl)oxyl (TEMPO) as the mediator has the remarkable capability of oxidizing 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Under optimal reaction conditions, a quantitative yield (90.2%) of FDCA with complete HMF conversion was obtained after 96h of reaction. More importantly, the magnetic laccase catalyst exhibited good recyclability and stability, maintaining 84.8% of its original activity following six reuse cycles. This is the first report on the efficient catalytic oxidation of HMF to FDCA by using an immobilized enzyme catalyst.
KeywordEnzyme Catalysis Furandicarboxylic Acid Hydroxymethylfurfural Immobilization Laccase
SubtypeArticle
WOS HeadingsScience & Technology ; Life Sciences & Biomedicine
DOI10.1002/cbic.201800008
Indexed BySCI
Language英语
WOS KeywordMESOPOROUS SILICA NANOPARTICLES ; AEROBIC OXIDATION ; CARBOXYLIC-ACIDS ; IMMOBILIZATION ; PERFORMANCE ; BIOMASS ; PURIFICATION ; FABRICATION ; CONVERSION ; OXIDASE
WOS Research AreaBiochemistry & Molecular Biology ; Pharmacology & Pharmacy
WOS SubjectBiochemistry & Molecular Biology ; Chemistry, Medicinal
Funding OrganizationNational Natural Science Foundation of China(21476242) ; National Key Technology Research and Development Program of China(2015BAK45B01) ; National Basic Research Program (973 Program) of China(2013CB733600) ; Key Research and Development Project of Shandong Province(2016GGX102005)
WOS IDWOS:000429412800002
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/24156
Collection生化工程国家重点实验室
Affiliation1.Qingdao Univ, Inst Biochem Engn, Collaborat Innovat Ctr Marine Biomass Fibers Mat, Sch Mat Sci & Engn, Qingdao 266071, Peoples R China
2.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China
3.Qingdao Cent Hosp, Dept Urol, Qingdao 266042, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Ke-Feng,Liu, Chun-lei,Sui, Kun-yan,et al. Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst[J]. CHEMBIOCHEM,2018,19(7):654-659.
APA Wang, Ke-Feng,Liu, Chun-lei,Sui, Kun-yan,Guo, Chen,&Liu, Chun-Zhao.(2018).Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst.CHEMBIOCHEM,19(7),654-659.
MLA Wang, Ke-Feng,et al."Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst".CHEMBIOCHEM 19.7(2018):654-659.
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