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Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst
Wang, Ke-Feng1,2,4; Liu, Chun-lei3; Sui, Kun-yan1; Guo, Chen2; Liu, Chun-Zhao1,2
2018-04-04
发表期刊CHEMBIOCHEM
ISSN1439-4227
卷号19期号:7页码:654-659
摘要2,5-Furandicarboxylic acid (FDCA) is a bio-based platform chemical for the production of polyethylene furanoate (PEF) and other valuable furanic chemicals. A magnetic laccase catalyst with (2,2,6,6-tetramethyl-piperidin-1-yl)oxyl (TEMPO) as the mediator has the remarkable capability of oxidizing 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Under optimal reaction conditions, a quantitative yield (90.2%) of FDCA with complete HMF conversion was obtained after 96h of reaction. More importantly, the magnetic laccase catalyst exhibited good recyclability and stability, maintaining 84.8% of its original activity following six reuse cycles. This is the first report on the efficient catalytic oxidation of HMF to FDCA by using an immobilized enzyme catalyst.
关键词Enzyme Catalysis Furandicarboxylic Acid Hydroxymethylfurfural Immobilization Laccase
文章类型Article
WOS标题词Science & Technology ; Life Sciences & Biomedicine
DOI10.1002/cbic.201800008
收录类别SCI
语种英语
关键词[WOS]MESOPOROUS SILICA NANOPARTICLES ; AEROBIC OXIDATION ; CARBOXYLIC-ACIDS ; IMMOBILIZATION ; PERFORMANCE ; BIOMASS ; PURIFICATION ; FABRICATION ; CONVERSION ; OXIDASE
WOS研究方向Biochemistry & Molecular Biology ; Pharmacology & Pharmacy
WOS类目Biochemistry & Molecular Biology ; Chemistry, Medicinal
项目资助者National Natural Science Foundation of China(21476242) ; National Key Technology Research and Development Program of China(2015BAK45B01) ; National Basic Research Program (973 Program) of China(2013CB733600) ; Key Research and Development Project of Shandong Province(2016GGX102005)
WOS记录号WOS:000429412800002
引用统计
文献类型期刊论文
条目标识符http://ir.ipe.ac.cn/handle/122111/24156
专题生化工程国家重点实验室
作者单位1.Qingdao Univ, Inst Biochem Engn, Collaborat Innovat Ctr Marine Biomass Fibers Mat, Sch Mat Sci & Engn, Qingdao 266071, Peoples R China
2.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China
3.Qingdao Cent Hosp, Dept Urol, Qingdao 266042, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Wang, Ke-Feng,Liu, Chun-lei,Sui, Kun-yan,et al. Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst[J]. CHEMBIOCHEM,2018,19(7):654-659.
APA Wang, Ke-Feng,Liu, Chun-lei,Sui, Kun-yan,Guo, Chen,&Liu, Chun-Zhao.(2018).Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst.CHEMBIOCHEM,19(7),654-659.
MLA Wang, Ke-Feng,et al."Efficient Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid by Magnetic Laccase Catalyst".CHEMBIOCHEM 19.7(2018):654-659.
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