CAS OpenIR  > 多相复杂系统国家重点实验室
Ionic liquid assisted synthesis of palladium nanoclusters for highly efficient formaldehyde oxidation
Zhang, Yimin1; Cao, Youhai1,2; Chen, Dong2; Cui, Penglei2; Yang, Jun2,3
2018-04-10
Source PublicationELECTROCHIMICA ACTA
ISSN0013-4686
Volume269Pages:38-44
Abstract

The use of Ionic Liquids (ILs) to enhance the electrocatalytic activity of metal nanoparticles has garnered sustained research interest. However, current strategies involving ionic liquids do not exploit their use and advantages in chemical synthesis of metal nanoparticles. Herein, we demonstrate a straightforward method, which combines the advantages of ILs in nanoparticle synthesis with the potentials of ILs in electrocatalysis, for the synthesis of Pd nanoclusters for electrochemical oxidation of formaldehyde. This method relies on the use of 1-(2'-aminoethyl)-3-methyl-imidazolum tetrafluoroborate ionic liquid as stabilizers to directly generate Pd nanoclusters with average sizes of 1.8 +/- 0.3 nm in a reaction medium consisting of water and methanol at room temperature. The electrochemical measurements prove that the ionic liquid-assisted Pd nanoclusters have mass-normalized activity approximately 7 times than that of commercial Pd/C catalysts for the oxidation of formaldehyde. (C) 2018 Elsevier Ltd. All rights reserved.

KeywordIonic Liquid Palladium Nanocluster Electrocatalysis Formaldehyde Oxidation Reaction
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.electacta.2018.02.155
Indexed BySCI
Language英语
WOS KeywordPhase-transfer Protocol ; Carbon-paste Electrode ; Electrocatalytic Activity ; Gold Nanoparticles ; Oxygen Reduction ; Electrochemical Biosensor ; Metal Nanoparticles ; Noble-metals ; Electrooxidation ; Catalyst
WOS Research AreaElectrochemistry
WOS SubjectElectrochemistry
Funding OrganizationNational Natural Science Foundation of China(21506234 ; National Natural Science Foundation of Beijing(2173062) ; Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences(COM2015A001 ; 21573240 ; MPCS-2017-A-02) ; 21706265)
WOS IDWOS:000428806700005
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/24198
Collection多相复杂系统国家重点实验室
Affiliation1.Tianjin Univ, State Minist Educ, Sch Chem Engn & Technol, Key Lab Green Chem Technol, Tianjin 300350, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yimin,Cao, Youhai,Chen, Dong,et al. Ionic liquid assisted synthesis of palladium nanoclusters for highly efficient formaldehyde oxidation[J]. ELECTROCHIMICA ACTA,2018,269:38-44.
APA Zhang, Yimin,Cao, Youhai,Chen, Dong,Cui, Penglei,&Yang, Jun.(2018).Ionic liquid assisted synthesis of palladium nanoclusters for highly efficient formaldehyde oxidation.ELECTROCHIMICA ACTA,269,38-44.
MLA Zhang, Yimin,et al."Ionic liquid assisted synthesis of palladium nanoclusters for highly efficient formaldehyde oxidation".ELECTROCHIMICA ACTA 269(2018):38-44.
Files in This Item:
File Name/Size DocType Version Access License
Ionic liquid assiste(1325KB)期刊论文出版稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, Yimin]'s Articles
[Cao, Youhai]'s Articles
[Chen, Dong]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, Yimin]'s Articles
[Cao, Youhai]'s Articles
[Chen, Dong]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Yimin]'s Articles
[Cao, Youhai]'s Articles
[Chen, Dong]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.