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Self-Assembled Composite Langmuir Films via Fluorine-Containing Bola-Type Derivative with Metal Ions
Qu, Nianrui1; Sun, Shuxin1; Zhao, Qianran1; Jiao, Tifeng1,2; Zhou, Jingxin1; Xing, Ruirui1,3; Gao, Faming1; Zhang, Lexin1; Peng, Qiuming2
2018-04-01
Source PublicationCOATINGS
ISSN2079-6412
Volume8Issue:4Pages:13
Abstract

The design and preparation of functional bolaamphiphile-based composite films are of key importance for application in a wide variety of fields. This study demonstrates a new approach to constructing composite films by the Langmuir-Blodgett (LB) method using a fluorine-containing bola-type diacid derivative with different metal ions. The bola-type molecule we used could be spread on water surfaces and metal ion subphases to fabricate various nanostructured ultrathin films. The obtained data demonstrated that the employed metal ions, including Ag(I), Cu(II), and Eu(III) ions in subphase solutions, can regulate the organized molecular stacking and form interfacial nanostructures deposited in LB films. It was found that the interfacial coordinating interactions can easily occur between carboxyl groups in a molecular skeleton with metal ions in the formed composite films. The formation of composite films was confirmed by changes in the surface pressure-area isotherms, morphologies, and spectra of the transferred LB films. While various research works have achieved the regulation of functions and nanostructures of sophisticated bola-type compounds, we here demonstrate a simple routine to modulate the nanostructures and organized packing of bola-type compounds composite films by changing the metal ions in subphase solutions.

KeywordComposite Langmuir Film Nanostructure Bola-type Diacid Fluorine-containing Spacer Self-assembly Metal Ion coordinatIon
DOI10.3390/coatings8040141
Language英语
WOS KeywordArchaebacterial Lipid Models ; Air/water Interface ; Blodgett-films ; Nucleotide Bolaamphiphiles ; Supramolecular Chirality ; Beta-cyclodextrin ; Supra-amphiphile ; Waste-water ; Monolayers ; Membranes
Funding ProjectNational Natural Science Foundation of China[21473153] ; National Natural Science Foundation of China[51771162] ; Support Program for the Top Young Talents of Hebei Province, China Postdoctoral Science Foundation[2015M580214] ; Scientific and Technological Research and Development Program of Qinhuangdao City[201701B004]
WOS Research AreaMaterials Science
WOS SubjectMaterials Science, Coatings & Films
Funding OrganizationNational Natural Science Foundation of China ; Support Program for the Top Young Talents of Hebei Province, China Postdoctoral Science Foundation ; Scientific and Technological Research and Development Program of Qinhuangdao City
WOS IDWOS:000435187300026
PublisherMDPI
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/24959
Collection生化工程国家重点实验室
Corresponding AuthorJiao, Tifeng
Affiliation1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
2.Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Qu, Nianrui,Sun, Shuxin,Zhao, Qianran,et al. Self-Assembled Composite Langmuir Films via Fluorine-Containing Bola-Type Derivative with Metal Ions[J]. COATINGS,2018,8(4):13.
APA Qu, Nianrui.,Sun, Shuxin.,Zhao, Qianran.,Jiao, Tifeng.,Zhou, Jingxin.,...&Peng, Qiuming.(2018).Self-Assembled Composite Langmuir Films via Fluorine-Containing Bola-Type Derivative with Metal Ions.COATINGS,8(4),13.
MLA Qu, Nianrui,et al."Self-Assembled Composite Langmuir Films via Fluorine-Containing Bola-Type Derivative with Metal Ions".COATINGS 8.4(2018):13.
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