CAS OpenIR
Nitrogen-Rich Ligands Directed Transition Metal (Co/Ni/Zn) 3,5-Dinitrobenzoic Acid Energetic Complexes: Syntheses, Crystal Structures and Properties
Li, Zhimin1; Zhang, Yanqiang2,3; Yuan, YuTao2,4; Jiao, Nianming2,4; Liu, Long2
2018-10-09
Source PublicationCHEMISTRYSELECT
ISSN2365-6549
Volume3Issue:37Pages:10298-10304
Abstract

Energetic transition metal (Co/Ni/Zn) complexes based on 3,5-dinitrobenzoic acid (DNBA), 1,5-diaminotetrazole (DAT), and semicarbazide (SCZ) were synthesized and characterized by elemental analysis and IR spectroscopy. The structures of the nine complexes were confirmed by single-crystal X-ray diffraction as: [Co(DNBA)(2)(H2O)(4)4(H2O)] (1), [Ni(DNBA)(2)(H2O)(4)4(H2O)] (2), [Zn(DNBA)(2)](n) (3), Co(SCZ)(2)(DNBA)(2) (4), Ni(SCZ)(2)(DNBA)(2) (5), Zn(SCZ)(2)(DNBA)(2) (6), Co(DAT)(2)(DNBA)(2)(H2O)(2) (7), Ni(DAT)(2)(DNBA)(2)(H2O)(2) (8), Zn(DAT)(2)(DNBA)(2)(H2O)(2) (9). It is worth mentioning that 3 exhibits a fascinating trigonal helical chain architecture bridged along the c-axis by Zn(II) and carboxylic O atoms. Differential scanning calorimetry (DSC) and thermogravimetry (TG) analyses were applied to assess the thermal decomposition processes and the non-isothermal kinetics parameters. The decomposition temperatures of 1-9 are in the range of 190 degrees C to 374 degrees C, which of 1, 2 and 3 are higher than 350 degrees C, 7 possesses the lowest decomposition temperatures. The nitro-rich ligands advanced the thermal decompositions of these complexes. The sensitivities toward impact and friction were tested according to a standard BAM method, and resulting that all the energetic complexes are much lower sensitive than primary explosive lead azide.

KeywordCoordination Compounds 1,5-diaminotetrazole 3,5-dinitrobenzoic Acid Energetic Materials Semicarbazide
DOI10.1002/slct.201802583
Language英语
WOS KeywordCoordination Polymers ; Thermal-properties ; Primary Explosives ; Lead Styphnate ; Sensitivity ; 1,5-diaminotetrazole ; Diversity ; Anion ; Salt
Funding ProjectBeijing Institute of Technology Research Fund Program for Young Scholars ; National Natural Science Foundation of China[21805008] ; National Natural Science Foundation of China[21376252] ; National Natural Science Foundation of China[21576270] ; National Natural Science Foundation of China[21406242] ; National Key Projects for Fundamental Research and Development of China[2016YFB0600903]
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
Funding OrganizationBeijing Institute of Technology Research Fund Program for Young Scholars ; National Natural Science Foundation of China ; National Key Projects for Fundamental Research and Development of China
WOS IDWOS:000446656900006
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/26277
Collection中国科学院过程工程研究所
Corresponding AuthorLi, Zhimin; Zhang, Yanqiang
Affiliation1.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Div Ion Liquids & Green Engn, Beijing 100190, Peoples R China
3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Henan, Peoples R China
4.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, Zhimin,Zhang, Yanqiang,Yuan, YuTao,et al. Nitrogen-Rich Ligands Directed Transition Metal (Co/Ni/Zn) 3,5-Dinitrobenzoic Acid Energetic Complexes: Syntheses, Crystal Structures and Properties[J]. CHEMISTRYSELECT,2018,3(37):10298-10304.
APA Li, Zhimin,Zhang, Yanqiang,Yuan, YuTao,Jiao, Nianming,&Liu, Long.(2018).Nitrogen-Rich Ligands Directed Transition Metal (Co/Ni/Zn) 3,5-Dinitrobenzoic Acid Energetic Complexes: Syntheses, Crystal Structures and Properties.CHEMISTRYSELECT,3(37),10298-10304.
MLA Li, Zhimin,et al."Nitrogen-Rich Ligands Directed Transition Metal (Co/Ni/Zn) 3,5-Dinitrobenzoic Acid Energetic Complexes: Syntheses, Crystal Structures and Properties".CHEMISTRYSELECT 3.37(2018):10298-10304.
Files in This Item:
File Name/Size DocType Version Access License
Nitrogen-Rich Ligand(883KB)期刊论文作者接受稿限制开放CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, Zhimin]'s Articles
[Zhang, Yanqiang]'s Articles
[Yuan, YuTao]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, Zhimin]'s Articles
[Zhang, Yanqiang]'s Articles
[Yuan, YuTao]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, Zhimin]'s Articles
[Zhang, Yanqiang]'s Articles
[Yuan, YuTao]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.