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Efficient Conversion of Cellulose to 5-Hydroxymethylfurfural in NaHSO4/ZrO2/H2O-THF Biphasic System
Fang, XW; Wang, Z; Yuan, B; Song, WL; Li, SG; Lin, WG; Fang, Xiaowei; Wang, Ze; Yuan, Bo; Song, Wenli; Li, Songgeng; Lin, Weigang
2018
Source PublicationCHEMISTRYSELECT
ISSN2365-6549
Volume3Issue:43Pages:12243
Abstract

5-hydroxymethylfurfural (HMF) is an important bio-based platform chemical for liquid fuel production. Herein, efficient conversion of cellulose to HMF in NaHSO4/ZrO2/H2O-THF biphasic system was investigated with a high HMF yield up to 86.5%. In the co-catalytic system, H+ ions given from NaHSO4 was promotive to all steps of the cellulose-to-HMF conversion; abundant alkaline sites of ZrO2 was particularly favorable to the glucose-to-fructose isomerization. The accelerated conversion of glucose as well as the fast extraction of HMF from aqueous phase to tetrahydrofuran (THF) phase, favored the inhibition of humins which was generated from condensation between glucose and HMF. Only a trace amount of humins over ZrO2 was detected after reaction, which guaranteed the reusability of ZrO2 in six running experiments without any post-treatment. The good reusability of ZrO2, the low -cost of NaHSO4, and the biomass-derived THF were advantageous for potential industrial application.

KeywordBiphasic System Ionic Liquids Cellulose Lignocellulosic Biomass 5-hydroxymethylfurfural Catalytic Conversion Nahso4 Water Zro2 Glucose Dehydration Products Fructose Tio2 Zro2
SubtypeArticle
DOI10.1002/slct.201802029
WOS IDWOS:000451062000033
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/26708
Collection中国科学院过程工程研究所
Recommended Citation
GB/T 7714
Fang, XW,Wang, Z,Yuan, B,et al. Efficient Conversion of Cellulose to 5-Hydroxymethylfurfural in NaHSO4/ZrO2/H2O-THF Biphasic System[J]. CHEMISTRYSELECT,2018,3(43):12243.
APA Fang, XW.,Wang, Z.,Yuan, B.,Song, WL.,Li, SG.,...&Lin, Weigang.(2018).Efficient Conversion of Cellulose to 5-Hydroxymethylfurfural in NaHSO4/ZrO2/H2O-THF Biphasic System.CHEMISTRYSELECT,3(43),12243.
MLA Fang, XW,et al."Efficient Conversion of Cellulose to 5-Hydroxymethylfurfural in NaHSO4/ZrO2/H2O-THF Biphasic System".CHEMISTRYSELECT 3.43(2018):12243.
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