Knowledge Management System Of Institute of process engineering,CAS
| Enhanced selective recovery of selenium from anode slime using MnO2 in dilute H2SO4 solution as oxidant | |
| Xiao, Li1,2; Wang, Yongliang1; Yu, Yang3; Fu, Guoyan1,2; Liu, Ya1,2; Sun, Zhi1; Ye, Shufeng1 | |
| 2019-02-01 | |
| Source Publication | JOURNAL OF CLEANER PRODUCTION
 |
| ISSN | 0959-6526 |
| Volume | 209Pages:494-504 |
| Abstract | As important rare raw material, Se and its compounds are widely used in metallurgy, glass manufacturing, chemicals and pigments, and electronics industry. However, current processes used for Se recovery are usually constrained by the serious pollution and high energy consumption. To dispose the issues in the process of Se recovery, this study developed an environmentally friendly process by using MnO2 in dilute H2SO4 as oxidant to efficiently recover Se and Cu. The effects of MnO2 dosage, H2SO4 concentrations, stirring speeds and temperature on the recovery were investigated. It was found that the major Se bearing phases in anode slime were elemental Se and Ag2Se. The oxidation capacity of MnO2 greatly increased with the H2SO4 concentration higher than 0.5 M and at a temperature above 60 degrees C. Optimum conditions derived from this study were 1.2 g MnO2 dosage, 1.0 M H2SO4, 600 rpm, and temperature at 80 degrees C, under which both the Se and Cu were recovered by 100% after 6 h. The cost-benefit analysis of the proposed process manifested that the profit of processing 1 t of anode slime was $ 82, and the sensitivity analysis showed that the price of Cu2Se and the Se recovery rate were the most important determinants of the profit. This research has great potential in Se recovery from anode slime. (C) 2018 Elsevier Ltd. All rights reserved. |
| Keyword | Selenium Copper Anode slime MnO2 Recovery |
| DOI | 10.1016/j.jclepro.2018.10.144 |
| Language | 英语 |
| WOS Keyword | X-RAY ; MANGANESE-DIOXIDE ; COPPER ; REDUCTION ; OXIDATION ; KINETICS ; SPECTROSCOPY ; EXTRACTION ; MECHANISM ; SULFUR |
| Funding Project | Key Deployment Project of the Chinese Academy of Sciences[ZDRW-ZS-2018-1-2] ; Material Chemistry and Engineering Group, Institute of Process Engineering, Chinese Academy of Sciences |
| WOS Research Area | Science & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology |
| WOS Subject | Green & Sustainable Science & Technology ; Engineering, Environmental ; Environmental Sciences |
| Funding Organization | Key Deployment Project of the Chinese Academy of Sciences ; Material Chemistry and Engineering Group, Institute of Process Engineering, Chinese Academy of Sciences |
| WOS ID | WOS:000457351900042 |
| Publisher | ELSEVIER SCI LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/27856 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Ye, Shufeng |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Jilin Jianzhu Univ, Sch Municipal & Environm Engn, Changchun 130117, Jilin, Peoples R China |
| Recommended Citation GB/T 7714 | Xiao, Li,Wang, Yongliang,Yu, Yang,et al. Enhanced selective recovery of selenium from anode slime using MnO2 in dilute H2SO4 solution as oxidant[J]. JOURNAL OF CLEANER PRODUCTION,2019,209:494-504. |
| APA | Xiao, Li.,Wang, Yongliang.,Yu, Yang.,Fu, Guoyan.,Liu, Ya.,...&Ye, Shufeng.(2019).Enhanced selective recovery of selenium from anode slime using MnO2 in dilute H2SO4 solution as oxidant.JOURNAL OF CLEANER PRODUCTION,209,494-504. |
| MLA | Xiao, Li,et al."Enhanced selective recovery of selenium from anode slime using MnO2 in dilute H2SO4 solution as oxidant".JOURNAL OF CLEANER PRODUCTION 209(2019):494-504. |
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