CAS OpenIR
Zr-Metal-Organic Frameworks Featuring TEMPO Radicals: Synergistic Effect between TEMPO and Hydrophilic Zr-Node Defects Boosting Aerobic Oxidation of Alcohols
Zhuang, Jin-Liang1; Liu, Xiang-Yue1; Zhang, Yu1; Wang, Chen1; Mao, Hui-Ling1; Guo, Jun1; Du, Xuan2; Zhu, Shao-Bin3; Ren, Bin4; Terfort, Andreas5
2019-01-23
Source PublicationACS APPLIED MATERIALS & INTERFACES
ISSN1944-8244
Volume11Issue:3Pages:3034-3043
AbstractMetal-organic frameworks (MOFs) featuring multiple catalytic units are excellent platforms for heterogeneous catalysis. However, the synergism between multiple catalytic units for catalysis is far from being well understood. Herein, we reported the synthesis of a robust 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) radical-functionalized Zr-MOF (UiO-68-TEMPO) in the form of single-crystalline and microsized crystals with varied missing linker defects. Detailed catalytic studies and theoretical calculations reveal that the synergistic effect between the TEMPO radicals and hydrophilic and defective Zr-nodes endows UiO-68-TEMPO with superior catalytic activity toward aerobic oxidation of alcohols. Our work not only offers a new route to design and synthesize highly effective MOF catalysts but also provides insights into the synergism between multiple catalytic sites.
Keywordmetal-organic frameworks TEMPO radical alcohol oxidation synergistic effect defects
DOI10.1021/acsami.8b18370
Language英语
WOS KeywordMISSING-LINKER DEFECTS ; CATALYSTS ; UIO-66 ; WATER ; FUNCTIONALIZATION ; DEPOSITION ; REACTIVITY ; CHEMISTRY ; SITES ; ACIDS
Funding ProjectNSFC[51302264] ; Natural Science Foundation of Guizhou Province[20161413] ; Department of Education of Guizhou Province[KY2017063] ; Department of Education of Guizhou Province[KYJJ2017016] ; State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University[201823]
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
Funding OrganizationNSFC ; Natural Science Foundation of Guizhou Province ; Department of Education of Guizhou Province ; State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University
WOS IDWOS:000457067300055
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/27883
Collection中国科学院过程工程研究所
Corresponding AuthorZhuang, Jin-Liang
Affiliation1.Guizhou Normal Univ, Sch Chem & Mat Sci, Key Lab Funct Mat Chem Guizhou Prov, Guiyang 550001, Guizhou, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Nat Engn Lab Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China
3.NanoFCM INC, Xiamen Pioneering Pk Overseas Chinese Scholars, Xiamen 361005, Peoples R China
4.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China
5.Goethe Univ Frankfurt, Inst Inorgan & Analyt Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany
Recommended Citation
GB/T 7714
Zhuang, Jin-Liang,Liu, Xiang-Yue,Zhang, Yu,et al. Zr-Metal-Organic Frameworks Featuring TEMPO Radicals: Synergistic Effect between TEMPO and Hydrophilic Zr-Node Defects Boosting Aerobic Oxidation of Alcohols[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(3):3034-3043.
APA Zhuang, Jin-Liang.,Liu, Xiang-Yue.,Zhang, Yu.,Wang, Chen.,Mao, Hui-Ling.,...&Terfort, Andreas.(2019).Zr-Metal-Organic Frameworks Featuring TEMPO Radicals: Synergistic Effect between TEMPO and Hydrophilic Zr-Node Defects Boosting Aerobic Oxidation of Alcohols.ACS APPLIED MATERIALS & INTERFACES,11(3),3034-3043.
MLA Zhuang, Jin-Liang,et al."Zr-Metal-Organic Frameworks Featuring TEMPO Radicals: Synergistic Effect between TEMPO and Hydrophilic Zr-Node Defects Boosting Aerobic Oxidation of Alcohols".ACS APPLIED MATERIALS & INTERFACES 11.3(2019):3034-3043.
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