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| Zr-Metal-Organic Frameworks Featuring TEMPO Radicals: Synergistic Effect between TEMPO and Hydrophilic Zr-Node Defects Boosting Aerobic Oxidation of Alcohols | |
| Zhuang, Jin-Liang1; Liu, Xiang-Yue1; Zhang, Yu1; Wang, Chen1; Mao, Hui-Ling1; Guo, Jun1; Du, Xuan2; Zhu, Shao-Bin3; Ren, Bin4; Terfort, Andreas5 | |
| 2019-01-23 | |
| Source Publication | ACS APPLIED MATERIALS & INTERFACES
 |
| ISSN | 1944-8244 |
| Volume | 11Issue:3Pages:3034-3043 |
| Abstract | Metal-organic frameworks (MOFs) featuring multiple catalytic units are excellent platforms for heterogeneous catalysis. However, the synergism between multiple catalytic units for catalysis is far from being well understood. Herein, we reported the synthesis of a robust 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) radical-functionalized Zr-MOF (UiO-68-TEMPO) in the form of single-crystalline and microsized crystals with varied missing linker defects. Detailed catalytic studies and theoretical calculations reveal that the synergistic effect between the TEMPO radicals and hydrophilic and defective Zr-nodes endows UiO-68-TEMPO with superior catalytic activity toward aerobic oxidation of alcohols. Our work not only offers a new route to design and synthesize highly effective MOF catalysts but also provides insights into the synergism between multiple catalytic sites. |
| Keyword | metal-organic frameworks TEMPO radical alcohol oxidation synergistic effect defects |
| DOI | 10.1021/acsami.8b18370 |
| Language | 英语 |
| WOS Keyword | MISSING-LINKER DEFECTS ; CATALYSTS ; UIO-66 ; WATER ; FUNCTIONALIZATION ; DEPOSITION ; REACTIVITY ; CHEMISTRY ; SITES ; ACIDS |
| Funding Project | NSFC[51302264] ; Natural Science Foundation of Guizhou Province[20161413] ; Department of Education of Guizhou Province[KY2017063] ; Department of Education of Guizhou Province[KYJJ2017016] ; State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University[201823] |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| Funding Organization | NSFC ; Natural Science Foundation of Guizhou Province ; Department of Education of Guizhou Province ; State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University |
| WOS ID | WOS:000457067300055 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/27883 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Zhuang, Jin-Liang |
| Affiliation | 1.Guizhou Normal Univ, Sch Chem & Mat Sci, Key Lab Funct Mat Chem Guizhou Prov, Guiyang 550001, Guizhou, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Nat Engn Lab Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China 3.NanoFCM INC, Xiamen Pioneering Pk Overseas Chinese Scholars, Xiamen 361005, Peoples R China 4.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China 5.Goethe Univ Frankfurt, Inst Inorgan & Analyt Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany |
| Recommended Citation GB/T 7714 | Zhuang, Jin-Liang,Liu, Xiang-Yue,Zhang, Yu,et al. Zr-Metal-Organic Frameworks Featuring TEMPO Radicals: Synergistic Effect between TEMPO and Hydrophilic Zr-Node Defects Boosting Aerobic Oxidation of Alcohols[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(3):3034-3043. |
| APA | Zhuang, Jin-Liang.,Liu, Xiang-Yue.,Zhang, Yu.,Wang, Chen.,Mao, Hui-Ling.,...&Terfort, Andreas.(2019).Zr-Metal-Organic Frameworks Featuring TEMPO Radicals: Synergistic Effect between TEMPO and Hydrophilic Zr-Node Defects Boosting Aerobic Oxidation of Alcohols.ACS APPLIED MATERIALS & INTERFACES,11(3),3034-3043. |
| MLA | Zhuang, Jin-Liang,et al."Zr-Metal-Organic Frameworks Featuring TEMPO Radicals: Synergistic Effect between TEMPO and Hydrophilic Zr-Node Defects Boosting Aerobic Oxidation of Alcohols".ACS APPLIED MATERIALS & INTERFACES 11.3(2019):3034-3043. |
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