Knowledge Management System Of Institute of process engineering,CAS
| Hierarchical biomimetic BiVO4 for the treatment of pharmaceutical wastewater in visible-light photocatalytic ozonation | |
| Liu, Xuelian1,2; Guo, Zhuang2; Zhou, Linbi1,2; Yang, Jin2; Cao, Hongbin1,2; Xiong, Mei2; Xie, Yongbing2; Jia, Guangru3 | |
| 2019-05-01 | |
| Source Publication | CHEMOSPHERE
 |
| ISSN | 0045-6535 |
| Volume | 222Pages:38-45 |
| Abstract | Photocatalytic ozonation is an attractive advanced oxidation process for wastewater treatment, but highly active catalysts with strong response to visible light are urgently needed to push forward its practical application. In this study, a hierarchical biomimetic monoclinic bismuth vanadate (BiVO4) with leaves morphology was synthesized by a hydrothermal method, and employed as catalyst for oxalic acid and penicillin degradation in photocatalytic ozonation. The results show that the organics degradation was more efficient using leaves shaped BiVO4 as catalyst than the bulk shaped one in photocatalytic ozonation and the synergy index is ranged from 2.8 to 3.3, indicating a superior positive synergistic effect between photocatalysis and ozonation. The higher activity of the leaves shaped BiVO4 was probably attributed to the distinctive biomimetic morphology and preferable band structure with more negative CB potential. Mechanism studies suggested that the main reactive species were h(+) and center dot OH for the degradation of persistent oxalic acid in photocatalytic ozonation. In addition, the effect of ozone concentration and inorganic ions and reusability of the material were also intensively investigated. (C) 2019 Elsevier Ltd. All rights reserved. |
| Keyword | BiVO4 Biomimetic morphology Photocatalytic ozonation Synergies Photogenerated hole |
| DOI | 10.1016/j.chemosphere.2019.01.084 |
| Language | 英语 |
| WOS Keyword | ADVANCED OXIDATION PROCESSES ; ORGANIC-COMPOUNDS ; DEGRADATION ; PERFORMANCE ; MECHANISM ; REMOVAL ; PHENOL ; ZNO ; G-C3N4 ; OZONE |
| Funding Project | Major Science and Technology Program for Water Pollution Control and Treatment[2017ZX07402001] ; Beijing Natural Science Foundation[8172043] ; National Science Fund for Distinguished Young Scholars of China[51425405] |
| WOS Research Area | Environmental Sciences & Ecology |
| WOS Subject | Environmental Sciences |
| Funding Organization | Major Science and Technology Program for Water Pollution Control and Treatment ; Beijing Natural Science Foundation ; National Science Fund for Distinguished Young Scholars of China |
| WOS ID | WOS:000462109200006 |
| Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/28222 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Xie, Yongbing |
| Affiliation | 1.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing Engn Res Ctr Proc Pollut Control, Beijing 100190, Peoples R China 3.HBIS Grp Hansteel Co, Handan 056015, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Xuelian,Guo, Zhuang,Zhou, Linbi,et al. Hierarchical biomimetic BiVO4 for the treatment of pharmaceutical wastewater in visible-light photocatalytic ozonation[J]. CHEMOSPHERE,2019,222:38-45. |
| APA | Liu, Xuelian.,Guo, Zhuang.,Zhou, Linbi.,Yang, Jin.,Cao, Hongbin.,...&Jia, Guangru.(2019).Hierarchical biomimetic BiVO4 for the treatment of pharmaceutical wastewater in visible-light photocatalytic ozonation.CHEMOSPHERE,222,38-45. |
| MLA | Liu, Xuelian,et al."Hierarchical biomimetic BiVO4 for the treatment of pharmaceutical wastewater in visible-light photocatalytic ozonation".CHEMOSPHERE 222(2019):38-45. |
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