Knowledge Management System Of Institute of process engineering,CAS
| Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base | |
| Lin, Yang1; Zhu, De-Ping2,3; Du, Yi-Ran2,3; Zhang, Rui1; Zhang, Suo-Jiang2,3; Xu, Bao-Hua2,3 | |
| 2019-04-19 | |
| Source Publication | ORGANIC LETTERS
 |
| ISSN | 1523-7060 |
| Volume | 21Issue:8Pages:2693-2698 |
| Abstract | The combination of tris(pyrazolyl)borate cobalt complexes and Lewis base is developed as an efficient catalyst precursor in the homogeneous hydrogenation. A broad substrate scope including carbonyls, alkenes, enamines, and imines is reduced with 60 atm of H-2 at 60 degrees C. Mechanistic studies support the hydrogenation operates through a frustrated Lewis pair (FLP)-like reduction process. These results highlight the development of novel non-noble metal catalytic processes, when combined with the diverse small molecule activation chemistry associated with FLPs. |
| DOI | 10.1021/acs.orglett.9b00679 |
| Language | 英语 |
| WOS Keyword | ASYMMETRIC HYDROGENATION ; SELECTIVE HYDROGENATION ; CARBENE INSERTION ; PINCER COMPLEXES ; CARBON-DIOXIDE ; IRON ; ACTIVATION ; LIGAND ; POLY(PYRAZOLYL)BORATE ; DEHYDROGENATION |
| Funding Project | National Natural Science Foundation of China[U1662133] ; National Natural Science Foundation of China[21374029] ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Organic |
| Funding Organization | National Natural Science Foundation of China ; K. C. Wong Education Foundation |
| WOS ID | WOS:000465644300043 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/28234 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Zhang, Rui; Xu, Bao-Hua |
| Affiliation | 1.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Lin, Yang,Zhu, De-Ping,Du, Yi-Ran,et al. Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base[J]. ORGANIC LETTERS,2019,21(8):2693-2698. |
| APA | Lin, Yang,Zhu, De-Ping,Du, Yi-Ran,Zhang, Rui,Zhang, Suo-Jiang,&Xu, Bao-Hua.(2019).Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base.ORGANIC LETTERS,21(8),2693-2698. |
| MLA | Lin, Yang,et al."Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base".ORGANIC LETTERS 21.8(2019):2693-2698. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment