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Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base
Lin, Yang1; Zhu, De-Ping2,3; Du, Yi-Ran2,3; Zhang, Rui1; Zhang, Suo-Jiang2,3; Xu, Bao-Hua2,3
2019-04-19
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume21Issue:8Pages:2693-2698
AbstractThe combination of tris(pyrazolyl)borate cobalt complexes and Lewis base is developed as an efficient catalyst precursor in the homogeneous hydrogenation. A broad substrate scope including carbonyls, alkenes, enamines, and imines is reduced with 60 atm of H-2 at 60 degrees C. Mechanistic studies support the hydrogenation operates through a frustrated Lewis pair (FLP)-like reduction process. These results highlight the development of novel non-noble metal catalytic processes, when combined with the diverse small molecule activation chemistry associated with FLPs.
DOI10.1021/acs.orglett.9b00679
Language英语
WOS KeywordASYMMETRIC HYDROGENATION ; SELECTIVE HYDROGENATION ; CARBENE INSERTION ; PINCER COMPLEXES ; CARBON-DIOXIDE ; IRON ; ACTIVATION ; LIGAND ; POLY(PYRAZOLYL)BORATE ; DEHYDROGENATION
Funding ProjectNational Natural Science Foundation of China[U1662133] ; National Natural Science Foundation of China[21374029] ; K. C. Wong Education Foundation[GJTD-2018-04]
WOS Research AreaChemistry
WOS SubjectChemistry, Organic
Funding OrganizationNational Natural Science Foundation of China ; K. C. Wong Education Foundation
WOS IDWOS:000465644300043
PublisherAMER CHEMICAL SOC
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Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/28234
Collection中国科学院过程工程研究所
Corresponding AuthorZhang, Rui; Xu, Bao-Hua
Affiliation1.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Lin, Yang,Zhu, De-Ping,Du, Yi-Ran,et al. Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base[J]. ORGANIC LETTERS,2019,21(8):2693-2698.
APA Lin, Yang,Zhu, De-Ping,Du, Yi-Ran,Zhang, Rui,Zhang, Suo-Jiang,&Xu, Bao-Hua.(2019).Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base.ORGANIC LETTERS,21(8),2693-2698.
MLA Lin, Yang,et al."Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base".ORGANIC LETTERS 21.8(2019):2693-2698.
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