CAS OpenIR
Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction
Qi, Xiaoxia1; Yan, Xirui1; Peng, Wencai1,2; Zhang, Jianshu1,2; Tong, Yanbin1; Li, Jun3; Sun, Dekui4; Hui, Ge4; Zhang, Jinli1,5
2019-03-28
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume43Issue:12Pages:4698-4705
AbstractHierarchical mesoporous MgO (HMM) is synthesized in the presence of graphene by a simple hydrothermal homogeneous precipitation route using urea as the precipitating reagent. Characterization of the HMM particles by means of spectroscopy and microscopy techniques, among others, indicates that HMM exposes the (111) crystal faces and possesses a specific surface area of 138 m(2) g(-1) and a pore size of about 0.33 m(2) g(-1). HMM exhibits higher activity for the Claisen-Schmidt condensation reaction than a conventionally prepared MgO catalyst, with a maximum turn over frequency of 1.34 x 10(-4) s(-1). Since the deactivation of the catalyst is mainly due to the formation of polyaromatic ketones in the reaction process, the catalyst can be readily regenerated through calcination.
DOI10.1039/c8nj05643a
Language英语
WOS KeywordCATALYTIC PERFORMANCE ; CHALCONES ; REDUCTION ; OXIDE ; ANALOGS ; NO
Funding ProjectApplied basic Research Program of Xinjiang Production and Construction Corps[2015AG400] ; Science & Technology Research and Achievement Transformation Project of Xinjiang Production and Construction Corps[2015AD027] ; Research Project of High-Level Talents Research of Shihezi University[RCZX201409] ; Training Program for Young Key Teachers of Shihezi University[CZ0211]
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
Funding OrganizationApplied basic Research Program of Xinjiang Production and Construction Corps ; Science & Technology Research and Achievement Transformation Project of Xinjiang Production and Construction Corps ; Research Project of High-Level Talents Research of Shihezi University ; Training Program for Young Key Teachers of Shihezi University
WOS IDWOS:000462541900004
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/28272
Collection中国科学院过程工程研究所
Corresponding AuthorPeng, Wencai; Li, Jun
Affiliation1.Shihezi Univ, Sch Chem & Chem Engn, Shihezi 832003, Xinjiang, Peoples R China
2.Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi, Xinjiang, Peoples R China
3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan, Shanxi, Peoples R China
5.Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Chem Engn Tianj, Key Lab Syst Bioengn MOE, Tianjin 300072, Peoples R China
Recommended Citation
GB/T 7714
Qi, Xiaoxia,Yan, Xirui,Peng, Wencai,et al. Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction[J]. NEW JOURNAL OF CHEMISTRY,2019,43(12):4698-4705.
APA Qi, Xiaoxia.,Yan, Xirui.,Peng, Wencai.,Zhang, Jianshu.,Tong, Yanbin.,...&Zhang, Jinli.(2019).Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction.NEW JOURNAL OF CHEMISTRY,43(12),4698-4705.
MLA Qi, Xiaoxia,et al."Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction".NEW JOURNAL OF CHEMISTRY 43.12(2019):4698-4705.
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