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In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution
Wang, Ze1,2; Fu, Zhaolin1,3; Lin, Weigang1,2; Li, Songgeng1,2; Song, Wenli1,2
2019-08-01
Source PublicationKOREAN JOURNAL OF CHEMICAL ENGINEERING
ISSN0256-1115
Volume36Issue:8Pages:1235-1242
AbstractIn-situ hydrodeoxygenation of furfural as a representative component in bio-oil was investigated in aqueous solution over supported Ni catalysts, for preparing furans as an antiknock additive. The addition of methanol, ethanol, or isopropanol was found inhibitive to coke formation at 220 degrees C. When using methanol as the hydrogen donor and coke inhibitor, the support in mesoporous structure with moderate acidity was more favorable to the conversion of furfural and to the formation of furans. An increased loading amount of Ni facilitated the generation of deep hydrogenated products. The conversion of furfural could hardly be changed under different methanol to water ratios, while the product distribution varied remarkably. Under optimized conditions, the summary yield of furan and 2-methylfuran reached to above 85%. On the basis of optimized reaction conditions, the in-situ hydrodeoxygenation of an eight-component synthetic bio-oil was tested, and the results verified the adaptability of the method for conversion of bio-oil.
KeywordFurfural 2-Methylfuran Hydrogen Donor Methanol In-situ Hydrodeoxygenation
DOI10.1007/s11814-019-0305-z
Language英语
WOS KeywordPYROLYSIS BIO-OIL ; HYDROGENATION ; BIOMASS ; HYDROTREATMENT ; BIOFUELS ; METHANOL ; PHENOL ; CONVERSION ; REDUCTION
Funding ProjectNational Natural Science Foundation of China[51476180] ; National Key R&D Program of China[2018YFB0605000]
WOS Research AreaChemistry ; Engineering
WOS SubjectChemistry, Multidisciplinary ; Engineering, Chemical
Funding OrganizationNational Natural Science Foundation of China ; National Key R&D Program of China
WOS IDWOS:000477989100003
PublisherKOREAN INSTITUTE CHEMICAL ENGINEERS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/30370
Collection中国科学院过程工程研究所
Corresponding AuthorWang, Ze
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100190, Peoples R China
3.Sinopec Res Inst Petr Proc, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Wang, Ze,Fu, Zhaolin,Lin, Weigang,et al. In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2019,36(8):1235-1242.
APA Wang, Ze,Fu, Zhaolin,Lin, Weigang,Li, Songgeng,&Song, Wenli.(2019).In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution.KOREAN JOURNAL OF CHEMICAL ENGINEERING,36(8),1235-1242.
MLA Wang, Ze,et al."In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution".KOREAN JOURNAL OF CHEMICAL ENGINEERING 36.8(2019):1235-1242.
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