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Recent Advances in Rochow-Muller Process Research: Driving to Molecular Catalysis and to A More Sustainable Silicone Industry
Zhang, Yu1,2; Li, Jing1; Liu, Hezhi1; Ji, Yongjun1,6; Zhong, Ziyi3,4; Su, Fabing1,5,6
2019-06-19
Source PublicationCHEMCATCHEM
ISSN1867-3880
Volume11Issue:12Pages:2757-2779
AbstractThe Rochow-Muller process, an old process that has been known for more than seventy years, is for the direct synthesis of methylchlorosilane. However, due to its unique economic efficiency, it is still extremely important in silicone industry, e. g., about 90 % of starting materials for producing silicones are obtained by this route. Although significant progress has been made in exploring high-efficient catalysts and understanding its mechanism, a quantitative description of this reaction is still far-fetched due to its high complexity. In addition, sustainable use and recycling of by-products and waste solid have become imperative nowadays due to the increasing demands for atom economy and environmental protection. This paper provides a comprehensive overview and insights into Rochow-Muller process from its catalysis to sustainable issues, including the catalyst development and reaction mechanism investigation, waste reutilization and their derived products. In addition, several emerging novel processes originated from Rochow-Muller process are summarized. Lastly, challenges and perspectives with respect to this reaction are discussed. We hope this work has accurately reflected and recorded the transition of Rochow-Muller process to modern molecular catalysis, and can promote a much more sustainable silicone industry.
KeywordRochow-Muller process Direct synthesis Cu-based catalysts sustainable utilization
DOI10.1002/cctc.201900385
Language英语
WOS KeywordCOPPER-BASED CATALYSTS ; CHEMICAL-VAPOR-DEPOSITION ; HIGH-CAPACITY ANODES ; SI-SI BOND ; CUO MICROSPHERES ; METHYL-CHLORIDE ; METHYLCHLOROSILANE FORMATION ; SOLVOTHERMAL SYNTHESIS ; GRAPHITE MICROSPHERES ; HYDROGEN-CHLORIDE
Funding ProjectNational Natural Science Foundation of China[21878301] ; China Scholarship Council[201804910755]
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
Funding OrganizationNational Natural Science Foundation of China ; China Scholarship Council
WOS IDWOS:000477935900002
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/30405
Collection中国科学院过程工程研究所
Corresponding AuthorZhong, Ziyi; Su, Fabing
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.GTIIT, Coll Engn, 241 Daxue Rd, Shantou 515063, Guangdong, Peoples R China
4.Technion Israel Inst Technol IIT, Dept Chem Engn, IL-32000 Haifa, Israel
5.Univ Chem Technol, Inst Ind Chem & Energy Technol, Shenyang 110142, Liaoning, Peoples R China
6.Zhongke Langfang Inst Proc Engn, Fenghua Rd 1,Langfang Econ & Tech Dev Zone, Langfang 065001, Hebei, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yu,Li, Jing,Liu, Hezhi,et al. Recent Advances in Rochow-Muller Process Research: Driving to Molecular Catalysis and to A More Sustainable Silicone Industry[J]. CHEMCATCHEM,2019,11(12):2757-2779.
APA Zhang, Yu,Li, Jing,Liu, Hezhi,Ji, Yongjun,Zhong, Ziyi,&Su, Fabing.(2019).Recent Advances in Rochow-Muller Process Research: Driving to Molecular Catalysis and to A More Sustainable Silicone Industry.CHEMCATCHEM,11(12),2757-2779.
MLA Zhang, Yu,et al."Recent Advances in Rochow-Muller Process Research: Driving to Molecular Catalysis and to A More Sustainable Silicone Industry".CHEMCATCHEM 11.12(2019):2757-2779.
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