Knowledge Management System Of Institute of process engineering,CAS
| Comparative study of mesoporous NixMn6-xCe4 composite oxides for NO catalytic oxidation | |
| Li Weiman1,2,3,4; Liu Haidi1; Zhang Min1,2; Chen Yunfa1,4 | |
| 2019-09-30 | |
| Source Publication | RSC ADVANCES
 |
| Volume | 9Issue:53Pages:31035-31042 |
| Abstract | In this work, a series of mesoporous NixMn6-xCe ternary oxides were prepared to investigate their NO catalytic oxidation ability. The sample Ni2Mn4Ce4 showed a 95% NO conversion at 210 degrees C (GHSV, similar to 80 000 h(-1)). Characterization results showed the good catalytic performance of Ni2Mn4Ce4 was due to its high specific surface area, more surface oxygen and high valance manganese species, which can be ascribed to the incorporation of three elements. Based on the results of XRD, H-2-TPR, O-2-TPD and XPS, we confirmed the existence of Ni3+ + Mn3+ -> Ni2+ + Mn4+, Ce4+ + Ni2+ -> Ce3+ + Ni3+ in Ni2Mn4Ce4, and the oxidation-reduction cycles were proved to be helpful for NO oxidation. The results from an in situ DRIFTS study indicated the presence of bidentate nitrate and monodentate nitrate species on the catalyst's surface. The nitrate species were proved to be intermediates for NO oxidation to NO2. A nitrogen circle mechanism was proposed to explain the possible route for NO oxidation. Nickel introduction was also helpful to improve the SO2 resistance of the NO oxidation reaction. The activity drop of Ni2Mn4Ce4 was 13.15% in the presence of SO2, better than Mn6Ce4 (25.29%). |
| DOI | 10.1039/c9ra05098a |
| Language | 英语 |
| WOS Keyword | LOW-TEMPERATURE SCR ; IN-SITU DRIFTS ; HIGHLY EFFICIENT ; CO OXIDATION ; REDUCTION ; MECHANISM ; PERFORMANCE ; MNOX-CEO2 ; AMMONIA ; FACILE |
| Funding Project | National Key Research and Development Plan[2016YFC0204100] ; National Key Research and Development Plan[2016YFC0204103] ; Control Strategy and Technology Integrated Demonstration of Industrial Source Pollution in Guanzhong area of China[ZDRW-ZS-2017-6-2] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| Funding Organization | National Key Research and Development Plan ; Control Strategy and Technology Integrated Demonstration of Industrial Source Pollution in Guanzhong area of China |
| WOS ID | WOS:000489652900050 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/31088 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Chen Yunfa |
| Affiliation | 1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 3.Zhongke Langfang Inst Proc Engn, Langfang Econ Tech Dev Zone, Fenghua Rd 1, Zhongke, Hebei, Peoples R China 4.CAS Ctr Excellence Urban Atmospher Environm, Xiamen 361021, Fujian, Peoples R China |
| Recommended Citation GB/T 7714 | Li Weiman,Liu Haidi,Zhang Min,et al. Comparative study of mesoporous NixMn6-xCe4 composite oxides for NO catalytic oxidation[J]. RSC ADVANCES,2019,9(53):31035-31042. |
| APA | Li Weiman,Liu Haidi,Zhang Min,&Chen Yunfa.(2019).Comparative study of mesoporous NixMn6-xCe4 composite oxides for NO catalytic oxidation.RSC ADVANCES,9(53),31035-31042. |
| MLA | Li Weiman,et al."Comparative study of mesoporous NixMn6-xCe4 composite oxides for NO catalytic oxidation".RSC ADVANCES 9.53(2019):31035-31042. |
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