Knowledge Management System Of Institute of process engineering,CAS
| Catalytic conversion of herbal residue carbohydrates to furanic derivatives in a deep eutectic solvent accompanied by dissolution and recrystallisation of choline chloride | |
| Yu, Qiang1,2; Song, Zhenlong3; Zhuang, Xinshu1; Liu, Li4; Qiu, Weihua5; Shi, Jiping4; Wang, Wen1; Li, Ying1; Wang, Zhongming1; Yuan, Zhenhong1 | |
| 2019-10-01 | |
| Source Publication | CELLULOSE
 |
| ISSN | 0969-0239 |
| Volume | 26Issue:15Pages:8263-8277 |
| Abstract | Catalytic conversion of lignocellulosic biomass into furfural (FF) and 5-hydroxymethylfurfural (5-HMF) requires a high reaction temperature (150-230 degrees C) in aqueous/organic systems. In this study, a novel choline chloride-formic acid-SnCl4-5H(2)O (ChCl-Fa-SnCl4) catalytic system was designed to transform herbal residues (HRs) carbohydrates into furanic derivatives at temperatures below 140 degrees C. The total yield of FF and xylose from HR of Heteropogon contortus (L.) Beauv (HRH) was 67.5% at 140 degrees C for 10 min, while the total yield of 5-HMF and glucose from HR of Anemarrhena asphodeloides Bunge was 93.8% at 120 degrees C. Characteristics of substrates such as molecular weight had a great influence on formation of furanic derivatives and sugar release. Surprisingly, the dissolution and recrystallisation characteristics of ChCl make this catalytic system sustainable and economically attractive. Recovery of ChCl and SnCl4 was 73.3% following simple natural recrystallisation, and recovered material retained a high chemical reactivity for FF and 5-HMF production. Moreover, 100% lignin dissolution was achieved in this system at 140 degrees C, and similar to 77% could be precipitated and recovered by adding water. |
| Keyword | Deep eutectic solvents Herb residues Furfural 5-Hydroxymethylfurfural |
| DOI | 10.1007/s10570-019-02372-6 |
| Language | 英语 |
| WOS Keyword | STRUCTURAL CHARACTERISTICS ; EXTRACTION RESIDUE ; PRETREATMENT ; EUCALYPTUS ; EFFICIENT ; ACID ; CYCLOPENTANONE ; HEMICELLULOSE ; PYROLYSIS ; CELLULOSE |
| Funding Project | National Natural Science Foundation of China[51876206] ; Natural Science Foundation of Guangdong Province[2018A030313012] ; Young Top-Notch Talent of Guangdong Province, China[2016TQ03N647] ; Pearl River S&T Nova Program of Guangzhou, China[201610010110] ; DNL Cooperation Fund, CAS[DNL180305] ; Youth Innovation Promotion Association, CAS[2015289] |
| WOS Research Area | Materials Science ; Polymer Science |
| WOS Subject | Materials Science, Paper & Wood ; Materials Science, Textiles ; Polymer Science |
| Funding Organization | National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province ; Young Top-Notch Talent of Guangdong Province, China ; Pearl River S&T Nova Program of Guangzhou, China ; DNL Cooperation Fund, CAS ; Youth Innovation Promotion Association, CAS |
| WOS ID | WOS:000489757400005 |
| Publisher | SPRINGER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/31171 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Wang, Wen; Li, Ying |
| Affiliation | 1.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 4.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China 5.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Yu, Qiang,Song, Zhenlong,Zhuang, Xinshu,et al. Catalytic conversion of herbal residue carbohydrates to furanic derivatives in a deep eutectic solvent accompanied by dissolution and recrystallisation of choline chloride[J]. CELLULOSE,2019,26(15):8263-8277. |
| APA | Yu, Qiang.,Song, Zhenlong.,Zhuang, Xinshu.,Liu, Li.,Qiu, Weihua.,...&Yuan, Zhenhong.(2019).Catalytic conversion of herbal residue carbohydrates to furanic derivatives in a deep eutectic solvent accompanied by dissolution and recrystallisation of choline chloride.CELLULOSE,26(15),8263-8277. |
| MLA | Yu, Qiang,et al."Catalytic conversion of herbal residue carbohydrates to furanic derivatives in a deep eutectic solvent accompanied by dissolution and recrystallisation of choline chloride".CELLULOSE 26.15(2019):8263-8277. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment