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| Thermodynamic Investigation of 1,3,5-Trioxane, Methyl Acrylate, Methyl Acetate, and Water Mixtures, in Terms of NRTL and UNIQUAC Models | |
| Zhao, Hui1,2; Li, Jie2; Wang, Lei2,3; Li, Chunshan2,3; Li, Ping4 | |
| 2019-10-02 | |
| Source Publication | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| ISSN | 0888-5885 |
| Volume | 58Issue:2Pages:18378-18386 |
| Abstract | The thermodynamics of 1,3,5-trioxane, methyl acrylate, methyl acetate, and water were systematically investigated, in terms of NRTL and UNIQUAC models. Solubility data of 1,3,5-trioxane in methyl acetate and methyl acrylate were reported. Vapor-liquid equilibria (VLE) data of 1,3,5-trioxane + methyl acetate and 1,3,5-trioxane + methyl acrylate binary systems were measured. The liquid-liquid equilibria (LLE) of 1,3,5-trioxane + methyl acrylate + water and 1,3,5-trioxane + methyl acrylate + methyl acetate + water mixtures were investigated. The thermodynamic consistency of VLE and LLE experimental data were tested by using Van Ness point method and Othmer-Tobias method, respectively. Binary interaction parameters for VLE and LLE systems were regressed and compared according to the average absolute deviation (AAD) and average absolute deviation in percentage (AAD%) values. Proper model and parameters were applied in the designed separation process of the quaternary mixture. |
| DOI | 10.1021/acs.iecr.9b02723 |
| Language | 英语 |
| WOS Keyword | VAPOR-LIQUID-EQUILIBRIUM ; PLUS WATER ; ISOPROPYL-ALCOHOL ; ACID PRODUCTION ; ACETIC-ACID ; SEPARATION ; METHANOL ; SYSTEM ; BINARY ; DISTILLATION |
| Funding Project | National Natural Science Funds[21878293] ; National Natural Science Funds[21576261] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH022] ; K.C.Wong Education Foundation[GJTD-2018-04] |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Chemical |
| Funding Organization | National Natural Science Funds ; Key Research Program of Frontier Sciences, CAS ; K.C.Wong Education Foundation |
| WOS ID | WOS:000489001800036 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/31217 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Li, Chunshan |
| Affiliation | 1.Univ Chinese Acad Sci, Beijing, Peoples R China 2.Chinese Acad Sci, Zhongke Langfang Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China 4.Ningxia Univ, Sch Chem & Chem Engn, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao, Hui,Li, Jie,Wang, Lei,et al. Thermodynamic Investigation of 1,3,5-Trioxane, Methyl Acrylate, Methyl Acetate, and Water Mixtures, in Terms of NRTL and UNIQUAC Models[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(2):18378-18386. |
| APA | Zhao, Hui,Li, Jie,Wang, Lei,Li, Chunshan,&Li, Ping.(2019).Thermodynamic Investigation of 1,3,5-Trioxane, Methyl Acrylate, Methyl Acetate, and Water Mixtures, in Terms of NRTL and UNIQUAC Models.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(2),18378-18386. |
| MLA | Zhao, Hui,et al."Thermodynamic Investigation of 1,3,5-Trioxane, Methyl Acrylate, Methyl Acetate, and Water Mixtures, in Terms of NRTL and UNIQUAC Models".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.2(2019):18378-18386. |
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