Knowledge Management System Of Institute of process engineering,CAS
| 二苯甲烷二异氰酸酯mdi聚合反应动力学研究 | |
| 张琴花; 李会泉; 柳海涛 | |
| 2011 | |
| Source Publication | 化学学报
 |
| ISSN | 0567-7351 |
| Volume | 69Issue:6Pages:605 |
| Abstract | The polymerization processes of methylene diphenyl diisocyanate (MDI) had been studied in flow atmosphere of high purity N(2) using TG-DSC-DTG techniques. The kinetic parameters of the polymerization process were calculated through the Flynn-Wall-Ozawa method and the polymerization raechanism of MDI was also studied with the Satava-Sestak and Coats-Redfern methods. The results indicated that: the process calculated could be attributed to the mechanism of random nucleation and subsequently growth, with the mechanism function being G(alpha)=-In(1-alpha)(1/2). The activation energy and pre-exponential factor were E=58.42 kJ/mol and A=5006 min(-1), the kinetic equation may be expressed as: -In(1-alpha)(1/2)=5006 Xexp(-58.42X1000)/8.314XT)t. |
| Language | 英语 |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/32032 |
| Collection | 中国科学院过程工程研究所 |
| Affiliation | 中国科学院过程工程研究所 |
| First Author Affilication | 中国科学院过程工程研究所 |
| Recommended Citation GB/T 7714 | 张琴花,李会泉,柳海涛. 二苯甲烷二异氰酸酯mdi聚合反应动力学研究[J]. 化学学报,2011,69(6):605. |
| APA | 张琴花,李会泉,&柳海涛.(2011).二苯甲烷二异氰酸酯mdi聚合反应动力学研究.化学学报,69(6),605. |
| MLA | 张琴花,et al."二苯甲烷二异氰酸酯mdi聚合反应动力学研究".化学学报 69.6(2011):605. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment