CAS OpenIR
preparationofpolyisobutylenebtertbutylacrylatebytransformationoflivingcarbocationicpolymerizationintoradicalpolymerization
He Jintai1; Ren Tianrui1; Cheng Bin2
2006
Source Publication合成橡胶工业
ISSN1000-1255
Volume029Issue:004Pages:301
Abstract使用BCl3/CH2Cl2/DTBP/IB反应体系实现了异丁烯的正离子聚合,得到末端为硼氧烷基的聚异丁烯,其与苯基溴化镁发生金属转移反应,生成末端为二苯基硼烷的聚异丁烯,其在常温下与氧气发生氧化反应,生成碳氧自由基,从而引发丙烯酸叔丁酯的自由基聚合,得到异丁烯和丙烯酸叔丁酯的嵌段聚合物。
Language英语
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/32049
Collection中国科学院过程工程研究所
Affiliation1.中国科学院过程工程研究所
2.北京化工大学
First Author Affilication中国科学院过程工程研究所
Recommended Citation
GB/T 7714
He Jintai,Ren Tianrui,Cheng Bin. preparationofpolyisobutylenebtertbutylacrylatebytransformationoflivingcarbocationicpolymerizationintoradicalpolymerization[J]. 合成橡胶工业,2006,029(004):301.
APA He Jintai,Ren Tianrui,&Cheng Bin.(2006).preparationofpolyisobutylenebtertbutylacrylatebytransformationoflivingcarbocationicpolymerizationintoradicalpolymerization.合成橡胶工业,029(004),301.
MLA He Jintai,et al."preparationofpolyisobutylenebtertbutylacrylatebytransformationoflivingcarbocationicpolymerizationintoradicalpolymerization".合成橡胶工业 029.004(2006):301.
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