highlyselectiveandstablehydrogenationofheavyaromaticnaphthaleneovertransitionmetalphosphides

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	highlyselectiveandstablehydrogenationofheavyaromaticnaphthaleneovertransitionmetalphosphides
	Usman Muhammad; Li Dan; Li Chunshan; Zhang Suojiang
	2015
Source Publication	sciencechinachemistry
ISSN	1674-7291
Volume	58 Issue:4 Pages:738
Abstract	The present study reports a highly selective and stable catalytic approach for producing tetralin, an important chemical, solvent, and H2 storage material. Transition metal phosphides (MoP, Ni2P, Co2P, and Fe2P) were prepared by wet impregnation and temperature-programmed reduction and characterized by x-ray diffraction (XRD), energy dispersive x-ray spectroscopy (EDX), EDX mapping, scanning electron microscopy (SEM), transmission electron microscopy (TEM), brunauer-emmett-teller (BET), temperature-programmed desorption of ammonia (NH3-TPD), and fourier transform infrared spectroscopy of pyridine (pyridine-FTIR). Of all the transition metal phosphides MoP was formed at a lower reduction temperature, which resulted in smaller particle size that enhanced the overall surface area of the catalyst. The existence of weak, moderate, and Lewis acidic sites over MoP were responsible for its high tetralin selectivity (90%) and stability during the 100 h reaction on-stream in a fixed-bed reactor.
Language	英语
Funding Project	[Special Funds of the National Natural Science Foundation of China] ; [National High Technology Research and Development Program of China] ; [National Natural Science Foundation of China (Petrochemical Joint Fund)]
Document Type	期刊论文
Identifier	http://ir.ipe.ac.cn/handle/122111/36324
Collection	中国科学院过程工程研究所
Affiliation	中国科学院过程工程研究所
First Author Affilication	中国科学院过程工程研究所
Recommended Citation GB/T 7714	Usman Muhammad,Li Dan,Li Chunshan,et al. highlyselectiveandstablehydrogenationofheavyaromaticnaphthaleneovertransitionmetalphosphides[J]. sciencechinachemistry,2015,58(4):738.
APA	Usman Muhammad,Li Dan,Li Chunshan,&Zhang Suojiang.(2015).highlyselectiveandstablehydrogenationofheavyaromaticnaphthaleneovertransitionmetalphosphides.sciencechinachemistry,58(4),738.
MLA	Usman Muhammad,et al."highlyselectiveandstablehydrogenationofheavyaromaticnaphthaleneovertransitionmetalphosphides".sciencechinachemistry 58.4(2015):738.

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