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Ionic liquid electrodeposition of Ge nano-film on Cu wire mesh as stable anodes for lithium-ion batteries | |
Liu, Lili1; Wang, Xiaoyang2; Zhang, Xiaohong2; Zhang, Xiuyun3; Chen, Shimou2 | |
2019-12-23 | |
Source Publication | IONICS
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ISSN | 0947-7047 |
Pages | 7 |
Abstract | Germanium-based materials as anode can improve the capacity of lithium-ion battery because of its excellent lithium-ion storage ability. But the application of Ge anode is hampered by the huge volume variation during de/lithiation processes. Herein, a Ge/Cu wire mesh (Ge/Cu-WM) electrode is prepared by ionic liquid electrodeposition, where the Ge nano-film is deposited on Cu wire mesh. The unique structure of Ge/Cu-WM electrode not only buffers the volume expansion but also enhances electron migration and electron transport during lithiation. The Cu3Ge is observed by XRD, which confirms that the Ge nano-film tightly attach to the Cu wires. All structural properties give the electrode excellent electrochemical performance, where a capacity of 633 mAh/g after 100 cycles at 0.1 C is obtained. The reasonable structure and improved cycling stability make Ge-based anodes highly attractive for lithium-ion battery applications. |
Keyword | Germanium Ionic liquid Electrodeposition Anode Lithium-ion battery |
DOI | 10.1007/s11581-019-03398-3 |
Language | 英语 |
WOS Keyword | HIGH-CAPACITY ; GERMANIUM ; COMPOSITE ; HOLLOW ; NANOPARTICLES ; NANOFIBERS ; ARRAYS ; CELL |
Funding Project | National Natural Science Foundation of China[51922099] ; National Natural Science Foundation of China[21503006] ; Research Foundation of Training Plan for Excellent Young Scholars of Beijing Technology and Business University |
WOS Research Area | Chemistry ; Electrochemistry ; Physics |
WOS Subject | Chemistry, Physical ; Electrochemistry ; Physics, Condensed Matter |
Funding Organization | National Natural Science Foundation of China ; Research Foundation of Training Plan for Excellent Young Scholars of Beijing Technology and Business University |
WOS ID | WOS:000504170000001 |
Publisher | SPRINGER HEIDELBERG |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/38602 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Chen, Shimou |
Affiliation | 1.Beijing Technol & Business Univ, Sch Sci, Dept Chem, Beijing 100048, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 3.Yangzhou Univ, Coll Phys Sci & Technol, Yangzhou 225002, Jiangsu, Peoples R China |
Corresponding Author Affilication | Center of lonic Liquids and Green Engineering |
Recommended Citation GB/T 7714 | Liu, Lili,Wang, Xiaoyang,Zhang, Xiaohong,et al. Ionic liquid electrodeposition of Ge nano-film on Cu wire mesh as stable anodes for lithium-ion batteries[J]. IONICS,2019:7. |
APA | Liu, Lili,Wang, Xiaoyang,Zhang, Xiaohong,Zhang, Xiuyun,&Chen, Shimou.(2019).Ionic liquid electrodeposition of Ge nano-film on Cu wire mesh as stable anodes for lithium-ion batteries.IONICS,7. |
MLA | Liu, Lili,et al."Ionic liquid electrodeposition of Ge nano-film on Cu wire mesh as stable anodes for lithium-ion batteries".IONICS (2019):7. |
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