CAS OpenIR
Synthesis of PdM (M = Zn, Cd, ZnCd) Nanosheets with an Unconventional Face Centered Tetragonal Phase as Highly Efficient Electrocatalysts for Ethanol Oxidation
Yun, Qinbai2,3; Lu, Qipeng2,4; Li, Cuiling2,5; Chen, Bo2; Zhang, Qinghua6; He, Qiyuan2; Hu, Zhaoning2; Zhang, Zhicheng2; Ge, Yiyao2; Yang, Nailiang2,7; Ge, Jingjie2; He, Yan-Bing8; Gu, Lin6,9,10; Zhang, Hua1,2
2019-12-01
Source PublicationACS NANO
ISSN1936-0851
Volume13Issue:12Pages:14329-14336
AbstractRecently, crystal-phase engineering has been emerging as a promising strategy to tune the physicochemical properties of noble metal catalysts and further improve their catalytic performance. However, the synthesis of noble metal catalysts with an unconventional crystal phase as well as desired composition and morphology still remains a great challenge. Herein, a series of PdM (M = Zn, Cd, ZnCd) nanosheets (NSs) with thickness less than 5 nm have been synthesized via a facile one-pot wet-chemical method. In particular, different from the conventional face -centered cubic (fcc) phase, PdM NSs possess an unconventional face-centered tetragonal (fct) phase. As a proof-of-concept application, the fct PdZn NSs exhibit significantly enhanced mass activity and stability in ethanol oxidation reaction, compared to the pure Pd NSs and commercial Pd black catalyst.
Keywordnanosheet crystal phase face-centered tetragonal palladium ethanol oxidation reaction
DOI10.1021/acsnano.9b07775
Language英语
WOS KeywordFEPT NANOPARTICLES ; OXYGEN-REDUCTION ; PALLADIUM ; ALLOY ; CO2
Funding ProjectMOE under AcRF Tier 2 in Singapore[MOE2015-T2-2-057] ; MOE under AcRF Tier 2 in Singapore[MOE2016-T2-2-103] ; MOE under AcRF Tier 2 in Singapore[MOE2017-T2-1-162] ; MOE under AcRF Tier 1 in Singapore[2016-T1-002-051] ; MOE under AcRF Tier 1 in Singapore[2017-T1-001-150] ; MOE under AcRF Tier 1 in Singapore[2017-T1-002-119] ; NTU under Start-Up Grant in Singapore[M4081296.070.500000] ; Agency for Science, Technology and Research (A*STAR) under its AME IRG in Singapore[A1783c0009] ; ITC via Hong Kong Branch of National Precious Metals Material Engineering Research Center ; Start-Up Grant from City University of Hong Kong
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
Funding OrganizationMOE under AcRF Tier 2 in Singapore ; MOE under AcRF Tier 1 in Singapore ; NTU under Start-Up Grant in Singapore ; Agency for Science, Technology and Research (A*STAR) under its AME IRG in Singapore ; ITC via Hong Kong Branch of National Precious Metals Material Engineering Research Center ; Start-Up Grant from City University of Hong Kong
WOS IDWOS:000505633300070
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/38636
Collection中国科学院过程工程研究所
Corresponding AuthorZhang, Hua
Affiliation1.City Univ Hong Kong, Dept Chem, Kowloon, Hong Kong, Peoples R China
2.Nanyang Technol Univ, Sch Mat Sci & Engn, Ctr Programmable Mat, SO Nanyang Ave, Singapore 639798, Singapore
3.Nanyang Technol Univ, Inst Sports Res, SO Nanyang Ave, Singapore 639798, Singapore
4.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
5.Beijing Inst Technol, Sch Chem & Chem Engn, Beijing Key Lab Photoelect Electrophoton Convers, Key Lab Cluster Sci,Minist Educ, Beijing 100081, Peoples R China
6.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
7.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 Beiertiao, Beijing 100190, Peoples R China
8.Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen Geim Graphene Ctr, Shenzhen 518055, Peoples R China
9.Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China
10.Collaborat Innovat Ctr Quantum Matter, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yun, Qinbai,Lu, Qipeng,Li, Cuiling,et al. Synthesis of PdM (M = Zn, Cd, ZnCd) Nanosheets with an Unconventional Face Centered Tetragonal Phase as Highly Efficient Electrocatalysts for Ethanol Oxidation[J]. ACS NANO,2019,13(12):14329-14336.
APA Yun, Qinbai.,Lu, Qipeng.,Li, Cuiling.,Chen, Bo.,Zhang, Qinghua.,...&Zhang, Hua.(2019).Synthesis of PdM (M = Zn, Cd, ZnCd) Nanosheets with an Unconventional Face Centered Tetragonal Phase as Highly Efficient Electrocatalysts for Ethanol Oxidation.ACS NANO,13(12),14329-14336.
MLA Yun, Qinbai,et al."Synthesis of PdM (M = Zn, Cd, ZnCd) Nanosheets with an Unconventional Face Centered Tetragonal Phase as Highly Efficient Electrocatalysts for Ethanol Oxidation".ACS NANO 13.12(2019):14329-14336.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yun, Qinbai]'s Articles
[Lu, Qipeng]'s Articles
[Li, Cuiling]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yun, Qinbai]'s Articles
[Lu, Qipeng]'s Articles
[Li, Cuiling]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yun, Qinbai]'s Articles
[Lu, Qipeng]'s Articles
[Li, Cuiling]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.