CAS OpenIR
Fabrication of inverse core-shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate)
Kikuchi, Shu1; Shoji, Ryoka1; Yoshida, Saki1; Kanehashi, Shinji1; Ma, Guang-Hui2; Ogino, Kenji1
2020-01-24
Source PublicationCOLLOID AND POLYMER SCIENCE
ISSN0303-402X
Pages11
AbstractWe here report the facile fabrication of inverse core-shell and Janus structured particles consisting of poly(4-butyltriphenylamine) (PBTPA) and poly(methyl methacrylate) (PMMA) via a solvent evaporation from solution droplets of a polymer blend dispersed in an aqueous phase. Janus structured composite particles in which the PBTPA domain was partially coated by the PMMA domain were obtained using poly(vinyl alcohol) (PVA) as a suspension stabilizer. On the other hand, when sodium dodecyl sulfate (SDS) was added as a surfactant together with PVA, "inverse core-shell" particles in which the PMMA core was covered by the PBTPA shell were formed as well as Janus particles. TEM observation showed that the PMMA core was located at the center of the sphere and PBTPA layer has uniform thickness in inverse core-shell particles. The increase of the composition of PBTPA or the concentration of SDS increased the ratio of the inverse core-shell particles to the Janus ones.
KeywordCore-shell Janus Phase separation Polymer blend Polymer particle Triphenylamine
DOI10.1007/s00396-020-04604-9
Language英语
WOS KeywordPARTICLE MORPHOLOGY DEVELOPMENT ; SEEDED EMULSION POLYMERIZATION ; COMPOSITE-PARTICLES ; MOLECULAR-WEIGHT ; POLYMERS ; COPOLYMER ; FRACTURE ; RUBBER ; LIGHT ; SHAPE
WOS Research AreaChemistry ; Polymer Science
WOS SubjectChemistry, Physical ; Polymer Science
WOS IDWOS:000509157800001
PublisherSPRINGER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/38741
Collection中国科学院过程工程研究所
Corresponding AuthorKanehashi, Shinji; Ogino, Kenji
Affiliation1.Tokyo Univ Agr & Technol, Grad Sch Bioapplicat & Syst Engn, 2-24-16 Nakacho, Koganei, Tokyo 1848588, Japan
2.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Kikuchi, Shu,Shoji, Ryoka,Yoshida, Saki,et al. Fabrication of inverse core-shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate)[J]. COLLOID AND POLYMER SCIENCE,2020:11.
APA Kikuchi, Shu,Shoji, Ryoka,Yoshida, Saki,Kanehashi, Shinji,Ma, Guang-Hui,&Ogino, Kenji.(2020).Fabrication of inverse core-shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate).COLLOID AND POLYMER SCIENCE,11.
MLA Kikuchi, Shu,et al."Fabrication of inverse core-shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate)".COLLOID AND POLYMER SCIENCE (2020):11.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Kikuchi, Shu]'s Articles
[Shoji, Ryoka]'s Articles
[Yoshida, Saki]'s Articles
Baidu academic
Similar articles in Baidu academic
[Kikuchi, Shu]'s Articles
[Shoji, Ryoka]'s Articles
[Yoshida, Saki]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Kikuchi, Shu]'s Articles
[Shoji, Ryoka]'s Articles
[Yoshida, Saki]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.