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| Synergistic engineering of architecture and composition in NixCo1-xMoO4@CoMoO4 nanobrush arrays towards efficient overall water splitting electrocatalysis | |
| Li, Zekun1; Zheng, Mingyue2; Zhao, Xian2; Yang, Jun3; Fan, Weiliu1 | |
| 2019-12-21 | |
| Source Publication | NANOSCALE
 |
| ISSN | 2040-3364 |
| Volume | 11Issue:47Pages:22820-22831 |
| Abstract | Implementing the hierarchical structures of non-noble-metal-based electrocatalysts and modulating their composition can help accelerate surface reactions and fulfill the promise of renewable energy devices via water splitting. Herein, molybdenum-based compounds are constructed on activated nickel foam (act-NF) by a one-step hydrothermal growth. The product generated on the act-NF is NixCo1-xMoO4@CoMoO4, with a novel 3D hierarchical heterostructure, wherein the one-dimensional CoMoO4 nanorods are hierarchically integrated with the two-dimensional NixCo1-xMoO4 nanosheets (NCMO@CMO/act-NF). The formation of NixCo1-xMoO4@CoMoO4 attributes to the release and diffusion of Ni2+ from act-NF. Heterogeneous NixCo1-xMoO4@CoMoO4 has compositional differences, and synergistic interaction between cobalt and nickel results in the modulated electronic states. Meanwhile, the hierarchical structure facilitates the exposure of active sites. Combining these two advantages, NCMO@CMO/act-NF presents a low eta(10) value of 61 and 180 mV in 1.0 M KOH for the HER and OER, respectively, and it shows a low cell voltage of 1.46 V for overall water splitting with robust stability. DFT calculations reveal that Ni doping leads to the charge depletion of Co, which further optimizes the d-band center of metal sites and tunes the adsorption of adsorbates to facilitate the water splitting reaction. Thus, a promising strategy of incorporating the nanostructure design with compositional modulation is presented to develop functional materials for energy conversion. |
| DOI | 10.1039/c9nr08281f |
| Language | 英语 |
| WOS Keyword | BIFUNCTIONAL ELECTROCATALYSTS ; NANOSHEET ARRAYS ; HIGHLY EFFICIENT ; NICKEL FOAM ; HYDROGEN ; ELECTRODE ; NANORODS ; NANOWIRES ; ALKALINE ; SYSTEMS |
| Funding Project | Natural Science Foundation of China[21771119] ; Taishan Scholar Project of Shandong Province |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS Subject | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
| Funding Organization | Natural Science Foundation of China ; Taishan Scholar Project of Shandong Province |
| WOS ID | WOS:000506887500013 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/38884 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Fan, Weiliu |
| Affiliation | 1.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China 2.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Zekun,Zheng, Mingyue,Zhao, Xian,et al. Synergistic engineering of architecture and composition in NixCo1-xMoO4@CoMoO4 nanobrush arrays towards efficient overall water splitting electrocatalysis[J]. NANOSCALE,2019,11(47):22820-22831. |
| APA | Li, Zekun,Zheng, Mingyue,Zhao, Xian,Yang, Jun,&Fan, Weiliu.(2019).Synergistic engineering of architecture and composition in NixCo1-xMoO4@CoMoO4 nanobrush arrays towards efficient overall water splitting electrocatalysis.NANOSCALE,11(47),22820-22831. |
| MLA | Li, Zekun,et al."Synergistic engineering of architecture and composition in NixCo1-xMoO4@CoMoO4 nanobrush arrays towards efficient overall water splitting electrocatalysis".NANOSCALE 11.47(2019):22820-22831. |
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