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Microstructures and Properties of Ceramic Fibers of h-BN Containing Amorphous Si3N4
Tan, Jing1,2; Ge, Min1; Yu, Shouquan1; Lu, Zhenxi1,2; Zhang, Weigang1,2
2019-12-01
Source PublicationMATERIALS
Volume12Issue:23Pages:9
AbstractComposite ceramic fibers comprising about 80 wt% boron nitride (h-BN) and 20 wt% Si3N4 were fabricated through melt-spinning, electron-beam curing, and pyrolysis up to 1600 degrees C in atmospheres of NH3 and N-2, using a mixture of poly[tri(methylamino)borazine] (PBN) and polysilazane (PSZ). By analyzing the microstructure and composition of the pyrolyzed ceramic fibers, we found the formation of binary phases including crystalline h-BN and amorphous Si3N4. Further investigations confirmed that this heterogeneous microstructure can only be formed when the introduced ratio of Si3N4 is below 30% in mass. The mean modulus and tensile strength of the fabricated composite fibers were about 90 GPa and 1040 MPa, twice the average of the pure h-BN fiber. The dielectric constant and dielectric loss tangent of the composite fibers is 3.06 and 2.94 x 10(-3).
Keywordpolymer-derived ceramics fibers boron nitride silicon nitride
DOI10.3390/ma12233812
Language英语
WOS KeywordPRECURSOR INFILTRATION ; NITRIDE ; COMPOSITES
Funding ProjectChinese Academy of Sciences ; National Natural Science Foundation of China[51472243] ; National Natural Science Foundation of China[51272251] ; Advance Research Fund[61409220401]
WOS Research AreaMaterials Science
WOS SubjectMaterials Science, Multidisciplinary
Funding OrganizationChinese Academy of Sciences ; National Natural Science Foundation of China ; Advance Research Fund
WOS IDWOS:000510178700008
PublisherMDPI
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/39173
Collection中国科学院过程工程研究所
Corresponding AuthorZhang, Weigang
Affiliation1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Tan, Jing,Ge, Min,Yu, Shouquan,et al. Microstructures and Properties of Ceramic Fibers of h-BN Containing Amorphous Si3N4[J]. MATERIALS,2019,12(23):9.
APA Tan, Jing,Ge, Min,Yu, Shouquan,Lu, Zhenxi,&Zhang, Weigang.(2019).Microstructures and Properties of Ceramic Fibers of h-BN Containing Amorphous Si3N4.MATERIALS,12(23),9.
MLA Tan, Jing,et al."Microstructures and Properties of Ceramic Fibers of h-BN Containing Amorphous Si3N4".MATERIALS 12.23(2019):9.
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