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Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols
Cai, Guangming1,2; Yang, Shaoqi1,2; Wang, Xinxin1; Zhou, Qing1,2; Xu, Junli1; Lu, Xingmei1,2
2020-04-07
Source PublicationJOURNAL OF SOLUTION CHEMISTRY
ISSN0095-9782
Pages35
Abstract2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate ([BHEM] [mesy]) displayed good ability for separating cellulose from biomass material in previous works. In order to have a better understanding of the structure-property relationship and facilitate further potential applications in industry, it is necessary to obtain more data for the physicochemical properties of [BHEM][mesy] and its mixtures. In this work, the densities (.) and viscosities (.) of [BHEM][mesy] + solvents (water, methanol, ethanol, n-propanol and isopropanol) mixtures were measured at six temperatures from (298.15 to 323.15) K over the full molar composition range and fitted by an empirical quadratic equation and Vogel-Fucher-Tammann (VFT) equation. Moreover, the excess molar volumes (VE) and viscosity deviation (..) of five binary mixtures were calculated and correlated by the Redlich-Kister equation. In addition, the apparent molar volumes ( V) and partial molar volumes ( V) of [BHEM][mesy] and solvents were also calculated and all these physicochemical property data (density, viscosity, excess molar properties as well as the apparent molar properties) are discussed in terms of the structure and interaction of binary mixtures.
KeywordPolyhydric protic ionic liquid Water Alcohols Density Viscosity
DOI10.1007/s10953-020-00968-2
Language英语
WOS KeywordVAPOR-LIQUID-EQUILIBRIA ; HIGH-PRESSURE DENSITIES ; PLUS METHYL ACETATE ; THERMOPHYSICAL PROPERTIES ; 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE ; COMPOSITION DEPENDENCE ; VOLUMETRIC PROPERTIES ; ENZYMATIC-HYDROLYSIS ; SURFACE-TENSION ; MOLAR VOLUME
Funding ProjectNational Natural Scientific Fund of China[21978291] ; National Natural Scientific Fund of China[21776289] ; National Natural Scientific Fund of China[21878292] ; National Natural Scientific Fund of China[21606240] ; K. C. Wong Education Foundation
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
Funding OrganizationNational Natural Scientific Fund of China ; K. C. Wong Education Foundation
WOS IDWOS:000524633500001
PublisherSPRINGER/PLENUM PUBLISHERS
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/40098
Collection中国科学院过程工程研究所
Corresponding AuthorZhou, Qing; Lu, Xingmei
Affiliation1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Cai, Guangming,Yang, Shaoqi,Wang, Xinxin,et al. Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols[J]. JOURNAL OF SOLUTION CHEMISTRY,2020:35.
APA Cai, Guangming,Yang, Shaoqi,Wang, Xinxin,Zhou, Qing,Xu, Junli,&Lu, Xingmei.(2020).Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols.JOURNAL OF SOLUTION CHEMISTRY,35.
MLA Cai, Guangming,et al."Densities and Viscosities of Binary Mixtures Containing the Polyhydric Protic Ionic Liquid(2-hydroxy-N-(2-hydroxyethyl)-N-methylethanaminium methanesulfonate) and Water or Alcohols".JOURNAL OF SOLUTION CHEMISTRY (2020):35.
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