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Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives | |
Cherevan, Alexey S.1; Nandan, Sreejith P.1; Roger, Isolda2; Liu, Rongji2,3; Streb, Carsten2,4; Eder, Dominik1 | |
2020-04-01 | |
Source Publication | ADVANCED SCIENCE
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Volume | 7Issue:8Pages:23 |
Abstract | Polyoxometalates (POMs) are molecular metal oxide clusters that feature a broad range of structures and functionalities, making them one of the most versatile classes of inorganic molecular materials. They have attracted widespread attention in homogeneous catalysis. Due to the challenges associated with their aggregation, precipitation, and degradation under operational conditions and to extend their scope of applications, various strategies of depositing POMs on heterogeneous substrates have been developed. Recent ground-breaking developments in the materials chemistry of supported POM composites are summarized and links between molecular-level understanding of POM-support interactions and macroscopic effects including new or optimized reactivities, improved stability, and novel function are established. Current limitations and future challenges in studying these complex composite materials are highlighted, and cutting-edge experimental and theoretical methods that will lead to an improved understanding of synergisms between POM and support material from the molecular through to the nano- and micrometer level are discussed. Future development in this fast-moving field is explored and emerging fields of research in POM heterogenization are identified. |
Keyword | charge transfer composites heterogenization molecular metal oxides substrates |
DOI | 10.1002/advs.201903511 |
Language | 英语 |
WOS Keyword | METAL-ORGANIC FRAMEWORKS ; GRAPHITIC CARBON NITRIDE ; WATER OXIDATION CATALYST ; HIGHLY EFFICIENT ; KEGGIN-TYPE ; TIO2 NANOPARTICLES ; ELECTRON-TRANSFER ; PHOTOCATALYTIC DEGRADATION ; HETEROGENEOUS CATALYST ; COMPOSITE ELECTRODES |
WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS Subject | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS ID | WOS:000529216500007 |
Publisher | WILEY |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/40366 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Cherevan, Alexey S.; Streb, Carsten; Eder, Dominik |
Affiliation | 1.Vienna Univ Technol, Inst Mat Chem, Getreidemarkt 9-BC-02, A-1060 Vienna, Austria 2.Ulm Univ, Inst Inorgan Chem 1, Albert Einstein Allee 11, D-89081 Ulm, Germany 3.Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 4.Helmholtz Inst Ulm, Helmholtzstr 11, D-89081 Ulm, Germany |
Recommended Citation GB/T 7714 | Cherevan, Alexey S.,Nandan, Sreejith P.,Roger, Isolda,et al. Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives[J]. ADVANCED SCIENCE,2020,7(8):23. |
APA | Cherevan, Alexey S.,Nandan, Sreejith P.,Roger, Isolda,Liu, Rongji,Streb, Carsten,&Eder, Dominik.(2020).Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives.ADVANCED SCIENCE,7(8),23. |
MLA | Cherevan, Alexey S.,et al."Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives".ADVANCED SCIENCE 7.8(2020):23. |
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