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A Flexible Ceramic/Polymer Hybrid Solid Electrolyte for Solid-State Lithium Metal Batteries
Pan, Kecheng1; Zhang, Lan2; Qian, Weiwei2; Wu, Xiangkun2; Dong, Kun2; Zhang, Haitao2; Zhang, Suojiang2
2020-04-01
Source PublicationADVANCED MATERIALS
ISSN0935-9648
Volume32Issue:17Pages:8
Abstract

Ceramic/polymer hybrid solid electrolytes (HSEs) have attracted worldwide attentions because they can overcome defects by combining the advantages of ceramic electrolytes (CEs) and solid polymer electrolytes (SPEs). However, the interface compatibility of CEs and SPEs in HSE limits their full function to a great extent. Herein, a flexible ceramic/polymer HSE is prepared via in situ coupling reaction. Ceramic and polymer are closely combined by strong chemical bonds, thus the problem of interface compatibility is resolved and the ions can transport rapidly by an expressway. The as-prepared membrane demonstrates an ionic conductivity of 9.83 x 10(-4) S cm(-1) at room temperature and a high Li+ transference numbers of 0.68. This in situ coupling reaction method provides an effective way to resolve the problem of interface compatibility.

KeywordIn Situ couplIng Lithium Metal Batteries Organic Inorganic Hybrids Solid Electrolytes Space Charge Layer
DOI10.1002/adma.202000399
Language英语
WOS KeywordIon-conducting Membrane ; Polymer Electrolytes ; Composite Electrolyte ; Dendrite Formation ; Peo-litfsi ; Binding ; Spectroscopy ; Enhancement ; Stability ; Chemistry
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000530300000006
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/40369
Collection中国科学院过程工程研究所
Corresponding AuthorZhang, Lan; Zhang, Suojiang
Affiliation1.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
2.Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Pan, Kecheng,Zhang, Lan,Qian, Weiwei,et al. A Flexible Ceramic/Polymer Hybrid Solid Electrolyte for Solid-State Lithium Metal Batteries[J]. ADVANCED MATERIALS,2020,32(17):8.
APA Pan, Kecheng.,Zhang, Lan.,Qian, Weiwei.,Wu, Xiangkun.,Dong, Kun.,...&Zhang, Suojiang.(2020).A Flexible Ceramic/Polymer Hybrid Solid Electrolyte for Solid-State Lithium Metal Batteries.ADVANCED MATERIALS,32(17),8.
MLA Pan, Kecheng,et al."A Flexible Ceramic/Polymer Hybrid Solid Electrolyte for Solid-State Lithium Metal Batteries".ADVANCED MATERIALS 32.17(2020):8.
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