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Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts
Zhang, Jimei1,2; Tian, Fuping3; Chen, Junwen4; Shi, Yanchun2; Cao, Hongbin2; Ning, Pengge2; Sun, Shanshan2; Xie, Yongbing2
2020-06-11
Source PublicationFRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
ISSN2095-0179
Pages11
AbstractA series of Ni/HZSM-5 and Ni/HIM-5 bi-functional catalysts were synthesized and applied to the aqueous-phase hydrodeoxygenation (HDO) of phenol. The Ni dispersibility and particle sizes were shown to be directly related to the porosity and crystal sizes of the parent zeolites, which further influenced the catalytic performances. The large pores and small crystal sizes of the parent zeolites were beneficial for dispersing Ni and forming small Ni particles, and the corresponding Ni/zeolite catalyst exhibited a higher phenol conversion and selectivity towards hydrocarbons. Importantly, the Ni/HIM-5 bi-functional catalyst exhibited a high activity (98.3%) and high selectivity for hydrocarbons (98.8%) when heated at 220 degrees C for 1 h and is thus a new potential catalyst for the HDO of phenolics to form hydrocarbons in the aqueous phase.
Keywordaqueous-phase hydrodeoxygenation phenol hydrocarbons Ni/HIM-5 bi-functional catalyst
DOI10.1007/s11705-020-1932-y
Language英语
WOS KeywordMODEL-COMPOUND ; PALMITIC ACID ; SUPPORTED NI ; HYDRODEOXYGENATION ; LIGNIN ; BIOMASS ; PYROLYSIS ; HYDROCARBONS ; NI/HZSM-5 ; GUAIACOL
Funding ProjectNational Natural Science Foundation of China[21908225] ; National Key Research and Development Program of China[2016YFB0600505] ; Youth Innovation Promotion Association, CAS[2014037]
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Natural Science Foundation of China ; National Key Research and Development Program of China ; Youth Innovation Promotion Association, CAS
WOS IDWOS:000539784400001
PublisherSPRINGER
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/41145
Collection中国科学院过程工程研究所
Corresponding AuthorXie, Yongbing
Affiliation1.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Dalian Univ Technol, Coll Chem, Dalian 116024, Peoples R China
4.SINOPEC, Res Inst Petr Proc, State Key Lab Catalyt Mat & React Engn, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Jimei,Tian, Fuping,Chen, Junwen,et al. Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts[J]. FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,2020:11.
APA Zhang, Jimei.,Tian, Fuping.,Chen, Junwen.,Shi, Yanchun.,Cao, Hongbin.,...&Xie, Yongbing.(2020).Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts.FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,11.
MLA Zhang, Jimei,et al."Conversion of phenol to cyclohexane in the aqueous phase over Ni/zeolite bi-functional catalysts".FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING (2020):11.
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