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Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation
Chen, Qiang1,2; Li, Tianhao2; Zhou, Yiming2; Bi, Yunfei3; Guo, Shuai4; Liu, Xuan2; Kang, Haozhe2; Wang, Mengyue2; Liu, Lei4; Xing, Enhui3; Yang, Dongyuan5,6
2020-07-01
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume59Issue:26Pages:12004-12012
AbstractPt nanoparticles encapsulated into zeolite Y (denoted as Pt@Y) exhibited approaching 100% catalytic selectivity to 2,5-bis-(hydroxymethyl)-furan (BHMF) at full conversion of 5-hydroxymethylfurfural (HMF) in the presence of H-2, coupled with good reusability. Zeolite Y constrained HMF to be adsorbed on encapsulated Pt nanoparticle surface via either the end of aldehyde groups or hydroxyl groups in thermodynamically unfavorable end-on mode to enlarge the gap in the activation energies between hydrogenation of aldehyde groups and hydrodehydroxylation of hydroxyl groups to favor selectivity enhancement via avoidance of further hydrodehydroxylation at moderate conditions, which provide a general method to avoid thermodynamics-regulated flat-lying conformation for simultaneous activation on the furan ring, aldehyde, and hydroxyl groups.
DOI10.1021/acs.iecr.0c01320
Language英语
WOS KeywordTOTAL-ENERGY CALCULATIONS ; METAL-CLUSTERS ; CO OXIDATION ; NANOPARTICLES ; EFFICIENT ; SIZE ; NANOCRYSTALS ; DISPERSION ; CATALYSTS ; ATOMS
Funding ProjectNational Natural Science Foundation of China[21706204] ; National Natural Science Foundation of China[51972264] ; China Petroleum AMP; Chemical Corporation[119004-2] ; CAS Pioneer Hundred Talents Program
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Natural Science Foundation of China ; China Petroleum AMP; Chemical Corporation ; CAS Pioneer Hundred Talents Program
WOS IDWOS:000547326800010
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/41281
Collection中国科学院过程工程研究所
Corresponding AuthorLiu, Lei; Xing, Enhui; Yang, Dongyuan
Affiliation1.Sun Yat Sen Univ, Sch Chem Engn & Technol, Zhuh Ai 519082, Peoples R China
2.Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Shaanxi, Peoples R China
3.Sinopec, Res Inst Petr Proc, Beijing 100083, Peoples R China
4.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
5.Shaanxi Yanchang Petr Grp Corp Ltd, Xian 710065, Shaanxi, Peoples R China
6.Dalian Inst Chem Phys, Xian Clean Energy Chem Res Inst, Xian 710065, Shaanxi, Peoples R China
Recommended Citation
GB/T 7714
Chen, Qiang,Li, Tianhao,Zhou, Yiming,et al. Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(26):12004-12012.
APA Chen, Qiang.,Li, Tianhao.,Zhou, Yiming.,Bi, Yunfei.,Guo, Shuai.,...&Yang, Dongyuan.(2020).Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(26),12004-12012.
MLA Chen, Qiang,et al."Selective Hydrogenation of 5-Hydroxymethylfurfural via Zeolite Encapsulation to Avoid Further Hydrodehydroxylation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.26(2020):12004-12012.
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