Knowledge Management System Of Institute of process engineering,CAS
| Molecule design of effective C2H4/C2H6 separation membranes: From 2D nanoporous graphene to 3D AHT zeolite | |
| Xu, Yinxiang1,2,3; Xu, Junbo3; Yang, Chao3,4 | |
| 2020-06-01 | |
| Source Publication | JOURNAL OF MEMBRANE SCIENCE
 |
| ISSN | 0376-7388 |
| Volume | 604Pages:8 |
| Abstract | It is of great importance and challenge to explore effective membranes with optimal pore structures from diverse porous materials to replace energy-intensive cryogenic distillation processes for C2H4/C2H6 separation because of their similar physical properties. In this work, we proposed a strategy to screen the ideal 3D zeolite membrane by matching the zeolite structure to the designed 2D nanopore. Here, we found out the ideal AHT zeolite membrane with elliptical windows similar to the designed graphene-embedded 22-crown-8 ether pore with ultrahigh selectivity of C2H4/C2H6 mixtures via molecular dynamics simulations. The results demonstrate that the AHT zeolite membrane only allows the transport of C2H4 based on molecular size exclusion, which is validated by density functional theory calculations. Furthermore, the permeation performance studies of pure components demonstrate that the AHT zeolite membrane exhibits a C2H4/C(2)H(6 )selectivity of around 100 and a C2H4 permeability of 958 Barrer, superior to most of reported membrane materials. |
| Keyword | AHT zeolite membrane C2H4/C2H6 separation Molecular sieving Molecular dynamics simulation |
| DOI | 10.1016/j.memsci.2020.118033 |
| Language | 英语 |
| WOS Keyword | IONIC LIQUID-MEMBRANES ; OLEFIN/PARAFFIN SEPARATION ; FACILITATED TRANSPORT ; ETHYLENE/ETHANE SEPARATION ; POLYMER MEMBRANES ; CARBON MEMBRANES ; GAS SEPARATION ; PERFORMANCE ; SELECTIVITY ; MIXTURES |
| Funding Project | National Key R&D Program of China[2016YFB0301702] ; National Natural Science Foundation of China[21878298] ; National Natural Science Foundation of China[51808362] ; National Natural Science Foundation of China[31961133018] ; Key Research Program of Frontier Sciences of CAS[QYZDJ-SSW-JSC030] ; Youth Innovation Research Project of Science and Technology Department in Sichuan[2017TD0027] ; DNL Cooperation Fund, CAS[DNL201902] ; Key Research Program of Provincial Science and Technology Department in Sichuan[2017SZ0167] ; Research Program of Sichuan Provincial Key Lab of Process Equipment and Control Engineering[GK201704] |
| WOS Research Area | Engineering ; Polymer Science |
| WOS Subject | Engineering, Chemical ; Polymer Science |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences of CAS ; Youth Innovation Research Project of Science and Technology Department in Sichuan ; DNL Cooperation Fund, CAS ; Key Research Program of Provincial Science and Technology Department in Sichuan ; Research Program of Sichuan Provincial Key Lab of Process Equipment and Control Engineering |
| WOS ID | WOS:000545790200005 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/41293 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Xu, Junbo; Yang, Chao |
| Affiliation | 1.Beihang Univ, Sch Space & Environm, Beijing 100191, Peoples R China 2.Sichuan Univ Sci & Engn, Coll Mech Engn, Zigong 643000, Sichuan, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Green Manufacture Inst, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Xu, Yinxiang,Xu, Junbo,Yang, Chao. Molecule design of effective C2H4/C2H6 separation membranes: From 2D nanoporous graphene to 3D AHT zeolite[J]. JOURNAL OF MEMBRANE SCIENCE,2020,604:8. |
| APA | Xu, Yinxiang,Xu, Junbo,&Yang, Chao.(2020).Molecule design of effective C2H4/C2H6 separation membranes: From 2D nanoporous graphene to 3D AHT zeolite.JOURNAL OF MEMBRANE SCIENCE,604,8. |
| MLA | Xu, Yinxiang,et al."Molecule design of effective C2H4/C2H6 separation membranes: From 2D nanoporous graphene to 3D AHT zeolite".JOURNAL OF MEMBRANE SCIENCE 604(2020):8. |
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