CAS OpenIR
Formation of Anomalous CuSn-shell/Pb-core Macrostructure in Cu-Sn-Pb Hypermonotectic Alloys
Li Jianqiang1,2; Sun Hong1,2; Ma Bingqian1
2020-02-01
Source PublicationRARE METAL MATERIALS AND ENGINEERING
ISSN1002-185X
Volume49Issue:2Pages:461-464
AbstractFor the core-shell structured immiscible alloys within the immiscible gap, whether the shell is composed of a phase with lower or higher melting point, has no exact answer yet. Based on the Cu-Sn-Pb calculated phase diagram given by reference, the phase separation of 14Sn-73.1Cu-12.9Pb, 14Sn-64.5Cu-21.5Pb, Cu-65Pb and Cu-75Pb alloys have been experimentally investigated by casting method. An anomalous core-shell structure with a CuSn-rich shell and a Pb-rich core forms in 14Sn-64.5Cu-21.5Pb alloy, which differs from the viewpoint that a lower melting point phase generally forms the shell as Cu-75Pb alloy shows. This anomalous phenomenon may be explained by the fact that the liquid separation reaction is suppressed due to undercooling generated during casting process and the monotectic reaction takes place before the liquid separation reaction. This work may provide a method to modify the structure of immiscible alloys through controlling the solidification path.
Keywordsolidification metals and alloys core-shell structure
Language英语
WOS KeywordIMMISCIBLE ALLOYS ; BI ; MICROSTRUCTURE ; SOLIDIFICATION ; MORPHOLOGIES
Funding ProjectNational Key Research and Development Program of China[2017YFC0703205] ; National Natural Science Foundation of China[51274182] ; Instrument Developing Project of the Chinese Academy of Sciences[YZ201520] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA15013500] ; "Transformational Technologies for Clean Energy and Demonstration", Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21070302]
WOS Research AreaMaterials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectMaterials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
Funding OrganizationNational Key Research and Development Program of China ; National Natural Science Foundation of China ; Instrument Developing Project of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; "Transformational Technologies for Clean Energy and Demonstration", Strategic Priority Research Program of the Chinese Academy of Sciences
WOS IDWOS:000550831700012
PublisherNORTHWEST INST NONFERROUS METAL RESEARCH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/41468
Collection中国科学院过程工程研究所
Corresponding AuthorLi Jianqiang
Affiliation1.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, CAS Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li Jianqiang,Sun Hong,Ma Bingqian. Formation of Anomalous CuSn-shell/Pb-core Macrostructure in Cu-Sn-Pb Hypermonotectic Alloys[J]. RARE METAL MATERIALS AND ENGINEERING,2020,49(2):461-464.
APA Li Jianqiang,Sun Hong,&Ma Bingqian.(2020).Formation of Anomalous CuSn-shell/Pb-core Macrostructure in Cu-Sn-Pb Hypermonotectic Alloys.RARE METAL MATERIALS AND ENGINEERING,49(2),461-464.
MLA Li Jianqiang,et al."Formation of Anomalous CuSn-shell/Pb-core Macrostructure in Cu-Sn-Pb Hypermonotectic Alloys".RARE METAL MATERIALS AND ENGINEERING 49.2(2020):461-464.
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