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Formation of Anomalous CuSn-shell/Pb-core Macrostructure in Cu-Sn-Pb Hypermonotectic Alloys | |
Li Jianqiang1,2; Sun Hong1,2; Ma Bingqian1 | |
2020-02-01 | |
Source Publication | RARE METAL MATERIALS AND ENGINEERING
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ISSN | 1002-185X |
Volume | 49Issue:2Pages:461-464 |
Abstract | For the core-shell structured immiscible alloys within the immiscible gap, whether the shell is composed of a phase with lower or higher melting point, has no exact answer yet. Based on the Cu-Sn-Pb calculated phase diagram given by reference, the phase separation of 14Sn-73.1Cu-12.9Pb, 14Sn-64.5Cu-21.5Pb, Cu-65Pb and Cu-75Pb alloys have been experimentally investigated by casting method. An anomalous core-shell structure with a CuSn-rich shell and a Pb-rich core forms in 14Sn-64.5Cu-21.5Pb alloy, which differs from the viewpoint that a lower melting point phase generally forms the shell as Cu-75Pb alloy shows. This anomalous phenomenon may be explained by the fact that the liquid separation reaction is suppressed due to undercooling generated during casting process and the monotectic reaction takes place before the liquid separation reaction. This work may provide a method to modify the structure of immiscible alloys through controlling the solidification path. |
Keyword | solidification metals and alloys core-shell structure |
Language | 英语 |
WOS Keyword | IMMISCIBLE ALLOYS ; BI ; MICROSTRUCTURE ; SOLIDIFICATION ; MORPHOLOGIES |
Funding Project | National Key Research and Development Program of China[2017YFC0703205] ; National Natural Science Foundation of China[51274182] ; Instrument Developing Project of the Chinese Academy of Sciences[YZ201520] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA15013500] ; "Transformational Technologies for Clean Energy and Demonstration", Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21070302] |
WOS Research Area | Materials Science ; Metallurgy & Metallurgical Engineering |
WOS Subject | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
Funding Organization | National Key Research and Development Program of China ; National Natural Science Foundation of China ; Instrument Developing Project of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; "Transformational Technologies for Clean Energy and Demonstration", Strategic Priority Research Program of the Chinese Academy of Sciences |
WOS ID | WOS:000550831700012 |
Publisher | NORTHWEST INST NONFERROUS METAL RESEARCH |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/41468 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Li Jianqiang |
Affiliation | 1.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, CAS Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Li Jianqiang,Sun Hong,Ma Bingqian. Formation of Anomalous CuSn-shell/Pb-core Macrostructure in Cu-Sn-Pb Hypermonotectic Alloys[J]. RARE METAL MATERIALS AND ENGINEERING,2020,49(2):461-464. |
APA | Li Jianqiang,Sun Hong,&Ma Bingqian.(2020).Formation of Anomalous CuSn-shell/Pb-core Macrostructure in Cu-Sn-Pb Hypermonotectic Alloys.RARE METAL MATERIALS AND ENGINEERING,49(2),461-464. |
MLA | Li Jianqiang,et al."Formation of Anomalous CuSn-shell/Pb-core Macrostructure in Cu-Sn-Pb Hypermonotectic Alloys".RARE METAL MATERIALS AND ENGINEERING 49.2(2020):461-464. |
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