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| Engineering Surface Atomic Architecture of NiTe Nanocrystals Toward Efficient Electrochemical N(2)Fixation | |
| Yuan, Menglei1,2; Li, Qiongguang1; Zhang, Jingxian1,2; Wu, Jiawen3; Zhao, Tongkun1,2; Liu, Zhanjun4; Zhou, Le1; He, Hongyan1; Li, Bin5; Zhang, Guangjin1,2 | |
| 2020-08-05 | |
| Source Publication | ADVANCED FUNCTIONAL MATERIALS
 |
| ISSN | 1616-301X |
| Pages | 9 |
| Abstract | Efficient N(2)fixation at ambient condition through electrochemical processes has been regarded as a promising alternative to traditional Haber-Bosch technology. Engineering surface atomic architecture of the catalysts to generate desirable active sites is important to facilitate electrochemical nitrogen reduction reaction (NRR) while suppressing the competitive hydrogen evolution reaction. Herein, nickel telluride nanocrystals with selectively exposed {001} and {010} facets are synthesized by a simple process, realizing the manipulation of surface chemistry at the atomic level. It is found that the catalysts expose the {001} facets coupled with desirable Ni sites, which possess high Faraday efficiency of 17.38 +/- 0.36% and NH(3)yield rate of 33.34 +/- 0.70 mu g h(-1)mg(-1)at -0.1 V vs RHE, outperforming other samples enclosed by {010} facets (8.56 +/- 0.22%, 12.78 +/- 0.43 mu g h(-1)mg(-1)). Both experimental results and computational simulations reveal that {001} facets, with selectively exposed Ni sites, guarantee the adsorption and activation of N(2)and weaken the binding for *H species. Moreover, the enhanced reduction capacity and accelerated charge transfer kinetics also contribute the superior NRR performance of {001} facets. This work presents a novel strategy in designing nonprecious NRR electrocatalyst with exposed favorable active sites. |
| Keyword | crystal facets nickel telluride nitrogen reduction reaction surface atomic architecture |
| DOI | 10.1002/adfm.202004208 |
| Language | 英语 |
| WOS Keyword | NITROGEN REDUCTION ; RATIONAL DESIGN ; N-2 ; AMMONIA ; FACET ; ELECTROCATALYSTS ; TEMPERATURE ; PERFORMANCE ; CO3O4 ; WATER |
| Funding Project | Ministry of Science and Technology of China ; Key Program for International S&T Cooperation Projects[2018YFE0124600] ; Cross Training Plan for High Level Talents in Beijing Colleges and Universities |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS Subject | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| Funding Organization | Ministry of Science and Technology of China ; Key Program for International S&T Cooperation Projects ; Cross Training Plan for High Level Talents in Beijing Colleges and Universities |
| WOS ID | WOS:000555442000001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/41556 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Li, Bin; Zhang, Guangjin |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Ctr Mat Sci & Optoeletron Engn, Beijing 100049, Peoples R China 3.Beijing Inst Graph Commun, Beijing Engn Res Ctr Printed Elect, Beijing 102600, Peoples R China 4.Chinese Acad Sci, Inst Coal Chem, CAS Key Lab Carbon Mat, Taiyuan 030001, Peoples R China 5.Zhengzhou Tobacco Res Inst CNTC, 2 Fengyang St, Zhengzhou 450001, Peoples R China |
| Recommended Citation GB/T 7714 | Yuan, Menglei,Li, Qiongguang,Zhang, Jingxian,et al. Engineering Surface Atomic Architecture of NiTe Nanocrystals Toward Efficient Electrochemical N(2)Fixation[J]. ADVANCED FUNCTIONAL MATERIALS,2020:9. |
| APA | Yuan, Menglei.,Li, Qiongguang.,Zhang, Jingxian.,Wu, Jiawen.,Zhao, Tongkun.,...&Zhang, Guangjin.(2020).Engineering Surface Atomic Architecture of NiTe Nanocrystals Toward Efficient Electrochemical N(2)Fixation.ADVANCED FUNCTIONAL MATERIALS,9. |
| MLA | Yuan, Menglei,et al."Engineering Surface Atomic Architecture of NiTe Nanocrystals Toward Efficient Electrochemical N(2)Fixation".ADVANCED FUNCTIONAL MATERIALS (2020):9. |
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