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| Thermal cycling stability of novel hexagonal boron nitride (h-BN)/glass compressive seals for planar intermediate temperature solid oxide fuel cells | |
| Li, Ruizhu1; Wang, Xiaochun1; Peng, Lian2; Jiang, Bowen1; Yang, Jiajun1; Yan, Dong1; Pu, Jian1; Chi, Bo1; Li, Jian1 | |
| 2020-11-30 | |
| Source Publication | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| ISSN | 0925-8388 |
| Volume | 843Pages:7 |
| Abstract | The novel h-BN/glass compressive seals were investigated for use in solid oxide fuel cell. The glass was mixed with h-BN powders to obtain composite materials using tape casting technique. Leakage rates were measured below 0.012 sccm/cm under input gas pressure of 6.8 kPa. Seals containing 40% by weight glass showed excellent thermal cycle and long-term operation stability. The leakage rates were reduced by more than half after ten thermal cycles under different input gas pressure. Also, the leakage rates gradually decreased to 0.008 sccm/cm under input gas pressure of 20.4 kPa at 750 degrees C during 208 h, and then remained stable. These observations can be explained by liquid B2O3 films having gradually formed on the h-BN surface. Boron oxidation effectively improved bondage for both interface and interior particles. This phenomenon was interpreted by seals' microstructure analyses and transmission electron microscopy. Finally, an evolution model is proposed to explain the process. (C) 2020 Elsevier B.V. All rights reserved. |
| Keyword | Solid oxide fuel cell Seals Leakage rates Boron nitride Thermal cycle stability |
| DOI | 10.1016/j.jallcom.2020.155620 |
| Language | 英语 |
| WOS Keyword | GLASS-CERAMIC SEALANT ; COMPOSITE SEALS ; OPTIMIZATION |
| Funding Project | National Science Foundation of China[51572099] ; National Science Foundation of China[51772114] ; National Defense Pre-Research Foundation of China[61402710102] ; National Key Research & Development Project-International Cooperation Program[2016YFE0126900] |
| WOS Research Area | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| WOS Subject | Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| Funding Organization | National Science Foundation of China ; National Defense Pre-Research Foundation of China ; National Key Research & Development Project-International Cooperation Program |
| WOS ID | WOS:000554894500004 |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/41572 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Pu, Jian |
| Affiliation | 1.Huazhong Univ Sci & Technol, Wuhan, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Ruizhu,Wang, Xiaochun,Peng, Lian,et al. Thermal cycling stability of novel hexagonal boron nitride (h-BN)/glass compressive seals for planar intermediate temperature solid oxide fuel cells[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2020,843:7. |
| APA | Li, Ruizhu.,Wang, Xiaochun.,Peng, Lian.,Jiang, Bowen.,Yang, Jiajun.,...&Li, Jian.(2020).Thermal cycling stability of novel hexagonal boron nitride (h-BN)/glass compressive seals for planar intermediate temperature solid oxide fuel cells.JOURNAL OF ALLOYS AND COMPOUNDS,843,7. |
| MLA | Li, Ruizhu,et al."Thermal cycling stability of novel hexagonal boron nitride (h-BN)/glass compressive seals for planar intermediate temperature solid oxide fuel cells".JOURNAL OF ALLOYS AND COMPOUNDS 843(2020):7. |
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