CAS OpenIR
Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines
Pan, Jia-Sheng1,2; Zhang, Rui1; Ma, Shuang-Shuang2,3; Han, Li-Jun2; Xu, Bao-Hua2,3
2020-09-22
Source PublicationCHEMISTRYSELECT
ISSN2365-6549
Volume5Issue:35Pages:10933-10938
AbstractAn easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H(2)and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.
KeywordHomogeneous catalysis Primary amines Reductive amination Ruthenium
DOI10.1002/slct.202002795
Language英语
WOS KeywordALKYL-ARYL KETONES ; REDUCTIVE AMINATION ; GENERAL-SYNTHESIS ; ASYMMETRIC HYDROGENATION ; SELECTIVE SYNTHESIS ; AQUEOUS AMMONIA ; N-ALKYLATION ; COMPLEXES ; ALCOHOLS ; NITRILES
Funding ProjectNational Natural Science Foundation of China (Petrochemical Joint Fund)[U1662133] ; National Natural Science Foundation of China (Petrochemical Joint Fund)[21374029] ; Key Research Program of Frontier Sciences, CAS[ZDBS-LY-JSC022] ; Zhengzhou High Level Talent Certificate[20180200052] ; K. C. Wong Education Foundation[GJTD-2018-04]
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
Funding OrganizationNational Natural Science Foundation of China (Petrochemical Joint Fund) ; Key Research Program of Frontier Sciences, CAS ; Zhengzhou High Level Talent Certificate ; K. C. Wong Education Foundation
WOS IDWOS:000571508100014
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/42174
Collection中国科学院过程工程研究所
Corresponding AuthorZhang, Rui; Xu, Bao-Hua
Affiliation1.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Pan, Jia-Sheng,Zhang, Rui,Ma, Shuang-Shuang,et al. Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines[J]. CHEMISTRYSELECT,2020,5(35):10933-10938.
APA Pan, Jia-Sheng,Zhang, Rui,Ma, Shuang-Shuang,Han, Li-Jun,&Xu, Bao-Hua.(2020).Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines.CHEMISTRYSELECT,5(35),10933-10938.
MLA Pan, Jia-Sheng,et al."Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines".CHEMISTRYSELECT 5.35(2020):10933-10938.
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