Knowledge Management System Of Institute of process engineering,CAS
| Curing behaviors and properties of epoxy resins with para-hexatomic ring blocks: Excellent comprehensive performances of tetrafluorophenyl | |
| Ma, Tian1; Ma, Jiahao1; Zhang, Junying1; Cheng, Jue1; Yang, Chao2 | |
| 2020-10-07 | |
| Source Publication | POLYMER
 |
| ISSN | 0032-3861 |
| Volume | 206Pages:10 |
| Abstract | It is a longstanding bottleneck for epoxies applied in high-tech fields to obtain integrated performances, including excellent thermal mechanical and stability properties, hydrophobicity, low permittivity and curing activation energy. A novel epoxy monomer with stiff tetrafluorophenyl backbone and robust intramolecular/intermolecular forces is expected to fundamentally break through this challenge. Herein, three model epoxy monomers with different symmetrical para-hexatomic ring blocks were synthesized, including tetrafluorophenyl-based (FEP), phenyl-based (TEREP) and cyclohexyl-based (CEP), followed by curing with methylhexahydrophthalic anhydride (MeHHPA) and polyetheramine (D230), respectively. As expected, TEREP showed better thermal mechanical properties than CEP due to closer stacking density and electronic effect. Noticeably, FEP self-consistently showed the best comprehensive properties among three resins, which mainly benefited from the introduced C-F bonds and the unique electronic effect caused by tetrafluorophenyl. Moreover, the exhilarating results of tetrafluorophenyl para-hexatomic ring provide an efficient guideline for building epoxy-based material genomes to better design future-oriented engineering materials. |
| Keyword | Excellent comprehensive performances Tetrafluorophenyl Para-hexatomic ring Non-isothermal curing kinetics Hydrophobicity Low permittivity |
| DOI | 10.1016/j.polymer.2020.122828 |
| Language | 英语 |
| WOS Keyword | REDUCED GRAPHENE OXIDE ; BISPHENOL-A ; MECHANICAL-PROPERTIES ; DIELECTRIC-CONSTANT ; DIGLYCIDYL ETHER ; T-G ; FLUORINE ; POLYMERIZATION ; NANOCOMPOSITES ; COMPOSITES |
| Funding Project | National Key Research Program[2016YFB0302000] |
| WOS Research Area | Polymer Science |
| WOS Subject | Polymer Science |
| Funding Organization | National Key Research Program |
| WOS ID | WOS:000576842800009 |
| Publisher | ELSEVIER SCI LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/42321 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Cheng, Jue; Yang, Chao |
| Affiliation | 1.Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | Ma, Tian,Ma, Jiahao,Zhang, Junying,et al. Curing behaviors and properties of epoxy resins with para-hexatomic ring blocks: Excellent comprehensive performances of tetrafluorophenyl[J]. POLYMER,2020,206:10. |
| APA | Ma, Tian,Ma, Jiahao,Zhang, Junying,Cheng, Jue,&Yang, Chao.(2020).Curing behaviors and properties of epoxy resins with para-hexatomic ring blocks: Excellent comprehensive performances of tetrafluorophenyl.POLYMER,206,10. |
| MLA | Ma, Tian,et al."Curing behaviors and properties of epoxy resins with para-hexatomic ring blocks: Excellent comprehensive performances of tetrafluorophenyl".POLYMER 206(2020):10. |
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