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| Excess spectroscopy and its applications in the study of solution chemistry | |
| Zhang, Yaqin1; Wu, Zhiwei1; Wang, Yaqian2; He, Hongyan1; Yu, Zhiwu2 | |
| 2020-10-01 | |
| Source Publication | PURE AND APPLIED CHEMISTRY
 |
| ISSN | 0033-4545 |
| Volume | 92Issue:10Pages:1611-1626 |
| Abstract | Characterization of structural heterogeneity of liquid solutions and the pursuit of its nature have been challenging tasks to solution chemists. In the last decade, an emerging method called excess spectroscopy has found applications in this area. The method, combining the merits of molecular spectroscopy and excess thermodynamic functions, shows the ability to enhance the apparent resolution of spectra, provides abundant information concerning solution structures and intermolecular interactions. In this review, the thinking and mathematics of the method, as well as its developments, are presented first. Then, research progress related to the exploration of the method is thoroughly reviewed. The materials are classified into two parts, small-molecular solutions and ionic liquid solutions. Finally, potential challenges and the perspective for further development of the method are discussed. |
| Keyword | excess spectroscopy hydrogen bond ICSC-36 ionic liquid micro heterogeneity solution structure |
| DOI | 10.1515/pac-2020-0107 |
| Language | 英语 |
| WOS Keyword | HYDROGEN-BONDING INTERACTIONS ; IONIC LIQUID ; BINARY-MIXTURES ; DIMETHYL-SULFOXIDE ; MOLECULAR-DYNAMICS ; ALIPHATIC-ALCOHOLS ; WATER ; MICROHETEROGENEITY ; ACETONITRILE ; SYSTEMS |
| Funding Project | National Science Fund for Excellent Young Scholars[21922813] ; National Natural Science Foundation of China[21733011] ; National Natural Science Foundation of China[21834006] ; Youth Innovation Promotion Association of CAS[2017066] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| Funding Organization | National Science Fund for Excellent Young Scholars ; National Natural Science Foundation of China ; Youth Innovation Promotion Association of CAS |
| WOS ID | WOS:000580659100008 |
| Publisher | WALTER DE GRUYTER GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/42455 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | He, Hongyan; Yu, Zhiwu |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China 2.Tsinghua Univ, Dept Chem, MOE Key Lab Bioorgan Phosphorous Chem & Chem Biol, Beijing 100084, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Yaqin,Wu, Zhiwei,Wang, Yaqian,et al. Excess spectroscopy and its applications in the study of solution chemistry[J]. PURE AND APPLIED CHEMISTRY,2020,92(10):1611-1626. |
| APA | Zhang, Yaqin,Wu, Zhiwei,Wang, Yaqian,He, Hongyan,&Yu, Zhiwu.(2020).Excess spectroscopy and its applications in the study of solution chemistry.PURE AND APPLIED CHEMISTRY,92(10),1611-1626. |
| MLA | Zhang, Yaqin,et al."Excess spectroscopy and its applications in the study of solution chemistry".PURE AND APPLIED CHEMISTRY 92.10(2020):1611-1626. |
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