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O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration
Li, Bin1; Liu, Yu1; Zhao, Xingting1; Ning, Ping1; Liu, Xiaolong2; Zhu, Tingyu2,3
2021-02-05
Source PublicationJOURNAL OF HAZARDOUS MATERIALS
ISSN0304-3894
Volume403Pages:13
AbstractDirecting to unwieldiness NOx emitted by the industry, the removal of NOx was implemented using yellow phosphorus (P-4) emulsion and red mud slurry as composite absorbent. Where yellow phosphorus is considered to stimulate formation of the ecological ozone (O-3) from O-2, the oxidation of insoluble NO into water-soluble NOx species by O-3, and the red mud as a pH buffer can be used to maintain the pH of the absorption liquid in a range that better absorbs NOx. NO is finally converted into NO2- and NO3-, whereas the yellow phosphorus is mainly PO43- . Single-factor influencing on the efficiency of denitration include the concentration of yellow phosphorus, reaction temperature, stirring intensity, gas flow rate, O-2 content, and red mud solid-liquid ratio were investigated. Response surface methodology (RSM) was used to optimize the process parameters. It was indicated that the removal rate of NOx can reach 99.3% under the optimal conditions. Moreover, the possible denitration reaction mechanism was also discussed.
KeywordYellow phosphorus Ozone Red mud Denitration
DOI10.1016/j.jhazmat.2020.123971
Language英语
WOS KeywordFLUE-GAS ; SIMULTANEOUS REMOVAL ; EFFICIENT REMOVAL ; NO ; SO2 ; NITROGEN ; NANOCOMPOSITE ; REDUCTION ; NH3
Funding ProjectMinistry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2019YFC0214404] ; Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2017YFC0210500] ; Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2017YFC0210600]
WOS Research AreaEngineering ; Environmental Sciences & Ecology
WOS SubjectEngineering, Environmental ; Environmental Sciences
Funding OrganizationMinistry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China
WOS IDWOS:000595080500001
PublisherELSEVIER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/42710
Collection中国科学院过程工程研究所
Corresponding AuthorNing, Ping; Liu, Xiaolong
Affiliation1.Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Yunnan, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod, Beijing Engn Res Ctr Proc Pollut Control, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Reg Atmospher Environm, Xiamen 361021, Peoples R China
Recommended Citation
GB/T 7714
Li, Bin,Liu, Yu,Zhao, Xingting,et al. O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration[J]. JOURNAL OF HAZARDOUS MATERIALS,2021,403:13.
APA Li, Bin,Liu, Yu,Zhao, Xingting,Ning, Ping,Liu, Xiaolong,&Zhu, Tingyu.(2021).O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration.JOURNAL OF HAZARDOUS MATERIALS,403,13.
MLA Li, Bin,et al."O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration".JOURNAL OF HAZARDOUS MATERIALS 403(2021):13.
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