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O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration | |
Li, Bin1; Liu, Yu1; Zhao, Xingting1; Ning, Ping1; Liu, Xiaolong2; Zhu, Tingyu2,3 | |
2021-02-05 | |
Source Publication | JOURNAL OF HAZARDOUS MATERIALS
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ISSN | 0304-3894 |
Volume | 403Pages:13 |
Abstract | Directing to unwieldiness NOx emitted by the industry, the removal of NOx was implemented using yellow phosphorus (P-4) emulsion and red mud slurry as composite absorbent. Where yellow phosphorus is considered to stimulate formation of the ecological ozone (O-3) from O-2, the oxidation of insoluble NO into water-soluble NOx species by O-3, and the red mud as a pH buffer can be used to maintain the pH of the absorption liquid in a range that better absorbs NOx. NO is finally converted into NO2- and NO3-, whereas the yellow phosphorus is mainly PO43- . Single-factor influencing on the efficiency of denitration include the concentration of yellow phosphorus, reaction temperature, stirring intensity, gas flow rate, O-2 content, and red mud solid-liquid ratio were investigated. Response surface methodology (RSM) was used to optimize the process parameters. It was indicated that the removal rate of NOx can reach 99.3% under the optimal conditions. Moreover, the possible denitration reaction mechanism was also discussed. |
Keyword | Yellow phosphorus Ozone Red mud Denitration |
DOI | 10.1016/j.jhazmat.2020.123971 |
Language | 英语 |
WOS Keyword | FLUE-GAS ; SIMULTANEOUS REMOVAL ; EFFICIENT REMOVAL ; NO ; SO2 ; NITROGEN ; NANOCOMPOSITE ; REDUCTION ; NH3 |
Funding Project | Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2019YFC0214404] ; Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2017YFC0210500] ; Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China[2017YFC0210600] |
WOS Research Area | Engineering ; Environmental Sciences & Ecology |
WOS Subject | Engineering, Environmental ; Environmental Sciences |
Funding Organization | Ministry of Science and Technoiogy of the People's Republic of China, National Key Research and Development Program of China |
WOS ID | WOS:000595080500001 |
Publisher | ELSEVIER |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/42710 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Ning, Ping; Liu, Xiaolong |
Affiliation | 1.Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Yunnan, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod, Beijing Engn Res Ctr Proc Pollut Control, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Reg Atmospher Environm, Xiamen 361021, Peoples R China |
Recommended Citation GB/T 7714 | Li, Bin,Liu, Yu,Zhao, Xingting,et al. O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration[J]. JOURNAL OF HAZARDOUS MATERIALS,2021,403:13. |
APA | Li, Bin,Liu, Yu,Zhao, Xingting,Ning, Ping,Liu, Xiaolong,&Zhu, Tingyu.(2021).O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration.JOURNAL OF HAZARDOUS MATERIALS,403,13. |
MLA | Li, Bin,et al."O-3 oxidation excited by yellow phosphorus emulsion coupling with red mud absorption for denitration".JOURNAL OF HAZARDOUS MATERIALS 403(2021):13. |
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