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A review on progress of lithium-rich manganese-based cathodes for lithium ion batteries
Ji, Xueqian1,2; Xia, Qing1,3,5; Xu, Yuxing1,3; Feng, Hailan1,3; Wang, Pengfei1,3; Tan, Qiangqiang1,3,4
2021-03-01
Source PublicationJOURNAL OF POWER SOURCES
ISSN0378-7753
Volume487Pages:20
AbstractWith the increasing demand for energy, layered lithium-rich manganese-based (Li-rich Mn-based) materials have attracted extensive attention because of their high capacity and high voltage. However, the Li-rich Mn-based materials suffer from a series of problems of oxygen release, transition metal (TM) migration, and structural transformation, which results in serious voltage and capacity decay. In this review, the lithium storage mechanism of the materials is systematically and critically summarized, in terms of the electrochemical performance problems such as large initial irreversible capacity, voltage decay, voltage hysteresis, inferior cycling performance, and electrolyte corrosion. We also summarize in detail the various modifications conducted in recent years, including component improvement, coating, doping, and surface treatment. Lastly, challenges and perspectives on future research directions for the development of high performance Li-rich Mn-based materials are also presented and discussed.
KeywordLithium ion batteries Cathode Li-rich Mn-based materials Oxygen redox Transition metal migration
DOI10.1016/j.jpowsour.2020.229362
Language英语
WOS KeywordENHANCED ELECTROCHEMICAL PERFORMANCE ; LAYERED OXIDE CATHODES ; POSITIVE-ELECTRODE MATERIALS ; HIGH-RATE CAPABILITY ; HIGH-CAPACITY ; SURFACE MODIFICATION ; SOLID-SOLUTION ; ANIONIC REDOX ; VOLTAGE FADE ; OXYGEN RELEASE
Funding ProjectNational Natural Science Foundation of China[51902310] ; Natural Science Foundation of Hebei Province[E2019103017] ; Natural Science Foundation of Hebei Province[E2019103018] ; Key R&D Program of Hebei Province[19214407D]
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary
Funding OrganizationNational Natural Science Foundation of China ; Natural Science Foundation of Hebei Province ; Key R&D Program of Hebei Province
WOS IDWOS:000609160700003
PublisherELSEVIER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/43283
Collection中国科学院过程工程研究所
Corresponding AuthorTan, Qiangqiang
Affiliation1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
3.Zhongke Langfang Inst Proc Engn, Langfang Econ & Tech Dev Zone, Langfang 065001, Peoples R China
4.Hebei Technol Innovat Ctr Adv Energy Mat, Langfang 065001, Peoples R China
5.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Ji, Xueqian,Xia, Qing,Xu, Yuxing,et al. A review on progress of lithium-rich manganese-based cathodes for lithium ion batteries[J]. JOURNAL OF POWER SOURCES,2021,487:20.
APA Ji, Xueqian,Xia, Qing,Xu, Yuxing,Feng, Hailan,Wang, Pengfei,&Tan, Qiangqiang.(2021).A review on progress of lithium-rich manganese-based cathodes for lithium ion batteries.JOURNAL OF POWER SOURCES,487,20.
MLA Ji, Xueqian,et al."A review on progress of lithium-rich manganese-based cathodes for lithium ion batteries".JOURNAL OF POWER SOURCES 487(2021):20.
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