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| Inducing two-dimensional single crystal TiN arrays with exposed {111} facets by a novel chemical vapor deposition with excellent electrocatalytic activity for hydrogen evolution reaction | |
| Xiang, Maoqiao1,2; Song, Miao1,3; Zhu, Qingshan1,3,4; Yang, Yafeng1,2; Hu, Chaoquan1,2; Liu, Zhiwei5; Zhao, Hongdan1,3; Ge, Yu1 | |
| 2021-01-15 | |
| Source Publication | CHEMICAL ENGINEERING JOURNAL
 |
| ISSN | 1385-8947 |
| Volume | 404Pages:8 |
| Abstract | Two-dimensional (2D) single crystal transition metal nitrides (TMNs) with exposed active crystal planes have great value for fundamental science and technological applications. However, it is still a great challenge to synthesize the non-layer crystal structured 2D single crystal TMNs, e.g. the face-centered cubic (FCC) 2D single crystal TiN, which would have distinct properties. Herein, for the first time, an induction-inhibition strategy was successfully developed to break through the intrinsic limitation and the weak anisotropic growth tendency of the FCC TiN. Single-crystalline TiN nanosheet (about 5.14 nm thickness) arrays with exposed {111} active facets were synthesized successfully on a large scale by the new strategy, where the layer arrays were induced by a layered TiNCl intermediate formed by the chemical vapor deposition reaction of a new titanium source (TiCl3) with NH3 and the exposed {111} facets was caused by the chemisorbed Cl inhibitor. The special 2D single crystal TiN arrays exhibited excellent catalytic activity and durability for hydrogen evolution reaction (HER) from water electrolysis. |
| Keyword | Induction-inhibition strategy Chemical vapor deposition Titanium nitride Nanosheets Hydrogen evolution reaction |
| DOI | 10.1016/j.cej.2020.126451 |
| Language | 英语 |
| WOS Keyword | MOS2 ULTRATHIN NANOSHEETS ; PHASE GROWTH ; CHEMISORPTION ; MESOCRYSTALS ; CRYSTALLIZATION ; TEMPERATURE ; NITRIDES ; GRAPHENE ; TIC(111) ; CARBIDES |
| Funding Project | Key Research Program of Frontier Sciences, Chinese Academy of Sciences[ZDBS-LY-JSC041] ; National Natural Science Foundation of China[11805227] ; Key Research Program of Nanjing IPE Institute of Green Manufacturing Industry[E0010708] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM-2019-A11] |
| WOS Research Area | Engineering |
| WOS Subject | Engineering, Environmental ; Engineering, Chemical |
| Funding Organization | Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; National Natural Science Foundation of China ; Key Research Program of Nanjing IPE Institute of Green Manufacturing Industry ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences |
| WOS ID | WOS:000609010200003 |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/43324 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Zhu, Qingshan; Yang, Yafeng |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Nanjing IPE Inst Green Mfg Ind, 266 Chuangyan Rd, Nanjing 211135, Peoples R China 3.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Innovat Acad Green Mfg, 1 North Second St, Beijing 100190, Peoples R China 5.Beijing Univ Technol, Coll Mat Sci & Engn, 100,Pingleyuan, Beijing 100124, Peoples R China |
| Recommended Citation GB/T 7714 | Xiang, Maoqiao,Song, Miao,Zhu, Qingshan,et al. Inducing two-dimensional single crystal TiN arrays with exposed {111} facets by a novel chemical vapor deposition with excellent electrocatalytic activity for hydrogen evolution reaction[J]. CHEMICAL ENGINEERING JOURNAL,2021,404:8. |
| APA | Xiang, Maoqiao.,Song, Miao.,Zhu, Qingshan.,Yang, Yafeng.,Hu, Chaoquan.,...&Ge, Yu.(2021).Inducing two-dimensional single crystal TiN arrays with exposed {111} facets by a novel chemical vapor deposition with excellent electrocatalytic activity for hydrogen evolution reaction.CHEMICAL ENGINEERING JOURNAL,404,8. |
| MLA | Xiang, Maoqiao,et al."Inducing two-dimensional single crystal TiN arrays with exposed {111} facets by a novel chemical vapor deposition with excellent electrocatalytic activity for hydrogen evolution reaction".CHEMICAL ENGINEERING JOURNAL 404(2021):8. |
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