CAS OpenIR
Design and Synthesis of La-Modified Copper Phyllosilicate Nanotubes for Hydrogenation of Methyl Acetate to Ethanol
Ren, Zhiheng1,2,3,4; Younis, Muhammad Naeem4,5; Wu, Hui4; Li, Chunshan4; Yang, Xiangui1,2,3; Wang, Gongying1,2,3
2021-02-13
Source PublicationCATALYSIS LETTERS
ISSN1011-372X
Pages14
AbstractA novel La modified copper phyllosilicate nanotubes (Cu-PSNT) were designed for hydrogenation of methyl acetate (MA) to ethanol. La/Cu-PSNT catalysts were prepared by the focus on the formation of unique tubular structure and evolution of copper species by varying La loading. The physicochemical properties and distribution of the copper species were systematically studied through several characterizations. The results showed that the Cu-PSNTs catalyst exhibited superior catalytic activity in comparison with the catalyst prepared by traditional ammonia-evaporation (AE method). Moreover, the addition of La greatly influenced the dispersion of active copper species and the ratio of Cu-0/(Cu-0 + Cu+) through the strong interplay between copper and lanthanum species. An appropriate amount of La could increase the surface area of active copper and enhance the ability to dissociate H-2 on La/Cu-PSNT catalyst, which were essential to increase the activity and stability in this hydrogenation reaction.
KeywordMethyl acetate Hydrogenation  processes and reactions Copper Ethanol Cu  +  Cu0
DOI10.1007/s10562-021-03555-2
Language英语
Funding ProjectKey Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH022] ; National Natural Science Funds (NSFC-NRCT)[51661145012] ; National Natural Science Funds (NSFC-NRCT)[Y71101A] ; K. C.Wong Education Foundation[GJTD-258 2018-04]
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
Funding OrganizationKey Research Program of Frontier Sciences, CAS ; National Natural Science Funds (NSFC-NRCT) ; K. C.Wong Education Foundation
WOS IDWOS:000617864300001
PublisherSPRINGER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/43526
Collection中国科学院过程工程研究所
Corresponding AuthorLi, Chunshan
Affiliation1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
2.Univ Chinese Acad Sci, Natl Engn Lab, Beijing 101408, Peoples R China
3.Univ Chinese Acad Sci, Technol, Beijing 101408, Peoples R China
4.Chinese Acad Sci, Zhongke Langfang Inst Proc Engn, Inst Proc Engn,Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Mu, Beijing 100190, Peoples R China
5.Univ Chinese Acad Sci, Beijing 101408, Peoples R China
Recommended Citation
GB/T 7714
Ren, Zhiheng,Younis, Muhammad Naeem,Wu, Hui,et al. Design and Synthesis of La-Modified Copper Phyllosilicate Nanotubes for Hydrogenation of Methyl Acetate to Ethanol[J]. CATALYSIS LETTERS,2021:14.
APA Ren, Zhiheng,Younis, Muhammad Naeem,Wu, Hui,Li, Chunshan,Yang, Xiangui,&Wang, Gongying.(2021).Design and Synthesis of La-Modified Copper Phyllosilicate Nanotubes for Hydrogenation of Methyl Acetate to Ethanol.CATALYSIS LETTERS,14.
MLA Ren, Zhiheng,et al."Design and Synthesis of La-Modified Copper Phyllosilicate Nanotubes for Hydrogenation of Methyl Acetate to Ethanol".CATALYSIS LETTERS (2021):14.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Ren, Zhiheng]'s Articles
[Younis, Muhammad Naeem]'s Articles
[Wu, Hui]'s Articles
Baidu academic
Similar articles in Baidu academic
[Ren, Zhiheng]'s Articles
[Younis, Muhammad Naeem]'s Articles
[Wu, Hui]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Ren, Zhiheng]'s Articles
[Younis, Muhammad Naeem]'s Articles
[Wu, Hui]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.