中国科学院过程工程研究所机构知识库

The desulfurization and dephosphorization performances have been considered to be the most challenging operations for refining ultra-clean steel. The distribution ratios of sulfur and phosphorus in the form of L-i = (%i)/[%i] as well as slag capacity concepts of sulfide and phosphate capacities in the form of Cim- proportional to (% i(m-)) have been extensively studied and widely applied for the description of desulfurization and dephosphorization abilities and potentials, respectively. However, the intrinsic limitations of two slag capacity concepts as sulfide and phosphate capacities regardless of slag oxygen potential p(O2) have seriously limited their direct applications into guiding the practical refining operations compared with the partitions or distribution ratios L-i. The theoretical limitations of sulfide and phosphate capacities have been extensively reviewed and critically assessed by comparison with the distribution ratios L-i in this contribution by taking two preferred thermodynamic conditions of both basic oxides concentration or slag basicity and slag oxygen potential as criteria. Meanwhile, the merits of two slag capacity concepts as measures for describing slag basicity like optical basicity have also been reviewed to be disruptive because the ratios of activity of free oxygen ion a(O2-) in slags to activity coefficients f(H, i) of sulfide and monomer phosphate PO43- in slags as implicit parameters in the defined two slag capacity concepts cannot hold constants in most complex slags. Furthermore, the limitations of phosphate capacity in two ways have been restated. Moreover, the oxygen potential p(O2) shows a great effect on plots of the desulfurization and dephosphorization abilities against two slag capacity concepts of slags at a given temperature. The abnormally higher oxygen potential pO2 can result in a suppression of the desulfurization ability of slags with a greater desulfurization potential, while the unreasonably smaller oxygen potential p(O2) can lead to a diminishing of the dephosphorization ability of slags with a larger dephosphorization potential. It has been verified by five case-studies covering desulfurization and dephosphorization operations that the partitions or distribution ratios L-i related to equilibrium quotients ki of desulfurization and dephosphorization reactions of Fe-based melts by slags can be in good accordance with two preferred thermodynamic conditions. The reasonable application of two slag capacity concepts is recommended to estimate or determine the distribution ratios between slags and Fe-based melts with the aid of activity a(%, O) of oxygen and activity coefficient f(%, i) of sulfur and phosphorus in Fe-base melts.