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| Dehydrative Formation of Isosorbide from Sorbitol over Poly(ionic liquid)-Covalent Organic Framework Hybrids | |
| Du, Yi-Ran1,2; Xu, Bao-Hua1,2; Xia, Shi-Ping1,3; Ding, Guang-Rong1,2; Zhang, Suo-Jiang1,2 | |
| 2021-01-13 | |
| Source Publication | ACS APPLIED MATERIALS & INTERFACES
 |
| ISSN | 1944-8244 |
| Volume | 13Issue:1Pages:552-562 |
| Abstract | In this study, the covalent bonding of linear poly(ionic liquids (PILs) with covalent organic frameworks (COFs) was accessed by copolymerization of a vinyl-decorated COF with 4-vinylbenzyl chloride, followed by quaternization with tertiary amines. The resultant PIL-COF composite by anchoring a proper content of vinyl sites on the COF-based comonomer retains the crystallinity and porosity, thereby facilitating access of the reactants to the catalytic active sites. As a proof of concept, the dehydrative transformation of sorbitol into isosorbide was selected as a benchmark reaction, whose rate improved significantly in the presence of PIL-COF-0.33 compared with those of individual components and the mesoporous PIL counterpart due to uniform pore sizes and flexible linear catalytic chains. In addition, the hybrids bearing a chemical cross-linkage between PILs and COFs are robust, and PIL-COF-0.33 can be recovered and reused for 10 runs without significant reactivity loss. These findings provide the basis for a novel design concept for achieving both efficient and stable IL catalysis. |
| Keyword | poly(ionic liquid)s covalent organic frameworks dehydration sorbitol isosorbide |
| DOI | 10.1021/acsami.0c18105 |
| Language | 英语 |
| WOS Keyword | IONIC LIQUID ; EFFICIENT ; CO2 ; CYCLOADDITION ; CATALYST |
| Funding Project | National Natural Science Foundation of China[U1704251] ; Key Research Program of Frontier Sciences, CAS[ZDBS-LY-JSC022] ; Major Program of National Natural Science Foundation of China[21890760] ; Zhengzhou High Level Talent Certificate[20180200052] ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| Funding Organization | National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Major Program of National Natural Science Foundation of China ; Zhengzhou High Level Talent Certificate ; K. C. Wong Education Foundation |
| WOS ID | WOS:000611066000050 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/43631 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Xu, Bao-Hua; Zhang, Suo-Jiang |
| Affiliation | 1.Chinese Acad Sci, Innovat Acad Green Manufacture, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China |
| Recommended Citation GB/T 7714 | Du, Yi-Ran,Xu, Bao-Hua,Xia, Shi-Ping,et al. Dehydrative Formation of Isosorbide from Sorbitol over Poly(ionic liquid)-Covalent Organic Framework Hybrids[J]. ACS APPLIED MATERIALS & INTERFACES,2021,13(1):552-562. |
| APA | Du, Yi-Ran,Xu, Bao-Hua,Xia, Shi-Ping,Ding, Guang-Rong,&Zhang, Suo-Jiang.(2021).Dehydrative Formation of Isosorbide from Sorbitol over Poly(ionic liquid)-Covalent Organic Framework Hybrids.ACS APPLIED MATERIALS & INTERFACES,13(1),552-562. |
| MLA | Du, Yi-Ran,et al."Dehydrative Formation of Isosorbide from Sorbitol over Poly(ionic liquid)-Covalent Organic Framework Hybrids".ACS APPLIED MATERIALS & INTERFACES 13.1(2021):552-562. |
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