CAS OpenIR
电动势法测量Na2PbO2和Na2ZnO2生成自由能
王志猛1; 谢宏伟1; 张懿2; 翟玉春1
2015
Source Publication中国有色金属学报
ISSN1004-0609
Volume000Issue:011Pages:3216
Abstract以PbO、ZnO和NaOH为原料,通过固相反应法制备出Na2PbO2和Na2ZnO2,并利用XRD对Na2PbO2和Na2ZnO2进行表征。采用β(β″)-Al2O3固体电解质管构建Pt∣PbO,Na2PbO2‖β(β″)-Al2O3‖NaCrO2,Cr2O3∣Pt和Pt∣ZnO,Na2ZnO2‖β(β″)-Al2O3‖NaCrO2,Cr2O3∣Pt电池,通过测量电池反应电动势,计算出Na2PbO2和Na2ZnO2的生成自由能,并得到其生成自由能与温度(700~1273K)的关系式。
Keyword电动势法 固相反应 生成自由能 β(β″)-Al2O3 固体电解质管
Language英语
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/43687
Collection中国科学院过程工程研究所
Affiliation1.东北大学
2.中国科学院过程工程研究所
Recommended Citation
GB/T 7714
王志猛,谢宏伟,张懿,等. 电动势法测量Na2PbO2和Na2ZnO2生成自由能[J]. 中国有色金属学报,2015,000(011):3216.
APA 王志猛,谢宏伟,张懿,&翟玉春.(2015).电动势法测量Na2PbO2和Na2ZnO2生成自由能.中国有色金属学报,000(011),3216.
MLA 王志猛,et al."电动势法测量Na2PbO2和Na2ZnO2生成自由能".中国有色金属学报 000.011(2015):3216.
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