Knowledge Management System Of Institute of process engineering,CAS
| Nanocapillarity and Nanoconfinement Effects of Pipet-like Bismuth@Carbon Nanotubes for Highly Efficient Electrocatalytic CO2 Reduction | |
| Zhang, Wenjun1,2,3; Yang, Songyuan1,3; Jiang, Minghang1,3; Hu, Yi1,3; Hu, Chaoquan4; Zhang, Xiaoli5; Jin, Zhong1,3 | |
| 2021-03-24 | |
| Source Publication | NANO LETTERS
 |
| ISSN | 1530-6984 |
| Volume | 21Issue:6Pages:2650-2657 |
| Abstract | Electrocatalytic CO2 reduction reaction is regarded as an intriguing route for producing renewable chemicals and fuels, but its development is limited by the lack of highly efficient and stable electrocatalysts. Herein, we propose the pipet-like bismuth (Bi) nanorods semifilled in nitrogen-doped carbon nanotubes (Bi-NRs@NCNTs) for highly selective electrocatalytic CO2 reduction. Benefited from the prominent capillary and confinement effects, the Bi-NRs@NCNTs act as nanoscale conveyors that can significantly facilitate the mass transport, adsorption,and concentration of reactants onto the active sites, realizing rapid reaction kinetics and low cathodic polarization. The spatial encapsulation and separation by the NCNT shells prevents the self-aggregation and surface oxidation of Bi-NRs, increasing the dispersity and stability of the electrocatalyst. As a result, the Bi-NRs@NCNTs exhibit high activity and durable catalytic stability for CO2-to-formate conversion over a wide potential range. The Faradaic efficiency for formate production reaches 90.9% at a moderate applied potential of -0.9 V vs reversible hydrogen electrode (RHE). |
| Keyword | electrochemical CO2 reduction formate production selectivity nanocapillarity nanoconfinement |
| DOI | 10.1021/acs.nanolett.1c00390 |
| Language | 英语 |
| Funding Project | National Key Research and Development Program of China[2017YFA0208200] ; Fundamental Research Funds for the Central Universities of China[0205-14380219] ; Fundamental Research Funds for the Central Universities of China[0205-14913212] ; NSFC[22022505] ; NSFC[21872069] ; NSFC[51761135104] ; Natural Science Foundation of Jiangsu Province[BK20180008] ; Shenzhen Fundamental Research Program of Science, Technology and Innovation Commission of Shenzhen Municipality[JCYJ20180307155007589] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS Subject | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| Funding Organization | National Key Research and Development Program of China ; Fundamental Research Funds for the Central Universities of China ; NSFC ; Natural Science Foundation of Jiangsu Province ; Shenzhen Fundamental Research Program of Science, Technology and Innovation Commission of Shenzhen Municipality |
| WOS ID | WOS:000634766600040 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/48197 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Hu, Chaoquan; Jin, Zhong |
| Affiliation | 1.Nanjing Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Adv Organ Mat, MOE Key Lab Mesoscop Chem,MOE Key Lab High Perfor, Nanjing 210023, Peoples R China 2.Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat F, Jiangsu Prov Key Lab Green Biomass Based Fuels &, Nanjing 210037, Peoples R China 3.Nanjing Univ, Shenzhen Res Inst, Shenzhen 518063, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 5.Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China |
| Corresponding Author Affilication | Center of lonic Liquids and Green Engineering |
| Recommended Citation GB/T 7714 | Zhang, Wenjun,Yang, Songyuan,Jiang, Minghang,et al. Nanocapillarity and Nanoconfinement Effects of Pipet-like Bismuth@Carbon Nanotubes for Highly Efficient Electrocatalytic CO2 Reduction[J]. NANO LETTERS,2021,21(6):2650-2657. |
| APA | Zhang, Wenjun.,Yang, Songyuan.,Jiang, Minghang.,Hu, Yi.,Hu, Chaoquan.,...&Jin, Zhong.(2021).Nanocapillarity and Nanoconfinement Effects of Pipet-like Bismuth@Carbon Nanotubes for Highly Efficient Electrocatalytic CO2 Reduction.NANO LETTERS,21(6),2650-2657. |
| MLA | Zhang, Wenjun,et al."Nanocapillarity and Nanoconfinement Effects of Pipet-like Bismuth@Carbon Nanotubes for Highly Efficient Electrocatalytic CO2 Reduction".NANO LETTERS 21.6(2021):2650-2657. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment