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Steam gasification of char derived from penicillin mycelial dreg and lignocellulosic biomass: Influence of P, K and Ca on char reactivity | |
Chen, Yuan1,2; Lin, Weigang1,2,3; Wu, Hao3; Jensen, Peter Arendt3; Song, Wenli1,2; Du, Lin1; Li, Songgeng1,2 | |
2021-08-01 | |
Source Publication | ENERGY
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ISSN | 0360-5442 |
Volume | 228Pages:8 |
Abstract | Gasification is a promising technology to dispose antibiotic mycelial dreg (AMD) which is a typical pharmaceutical hazardous bio-waste. However, the gasification of AMD is rarely studied. Since char gasification is the key step in the gasification process, the present work focused on the steam gasification of char. The influence of inorganic elements inside AMD char (mainly P, K and Ca) on the char gasification reactivity is investigated. Particularly, the effect of P on char gasification reactivity was deeply studied, and the co-effect of P, K and Ca on char gasification reactivity was firstly studied and explained. The obtained results suggested that P can deactivate the catalytic function of K and Ca on char gasification by forming K-phosphates and Ca-phosphates. The existence form of P can affect its inhibitory effect on K and Ca, and the pyrophosphate P had a stronger inhibiting effect than orthophosphate P. The deactivation of P on K is related to the ratio of K to P, and the bigger the ratio of K to P the less the deactivation of P on K. The existence of Ca can effectively eliminate the deactivation of P on K by reacting with P to form more stable Ca-3(PO4)(2). (C) 2021 Elsevier Ltd. All rights reserved. |
Keyword | Antibiotic mycelial dreg Gasification Char reactivity Inorganic elements |
DOI | 10.1016/j.energy.2021.120605 |
Language | 英语 |
WOS Keyword | PYROLYSIS ; DEGRADATION ; BEHAVIOR |
Funding Project | National Key R&D Program of China[2018YFC1901300] ; 2017 Doctoral International Cooperation Training Program of University of Chinese Academy of Sciences ; Combustion and Harmful Emission Control (CHEC) Research Centre at the Department of Chemical and Biochemical Engineering, Technical University of Denmark ; SinoDanish Center for Education and Research |
WOS Research Area | Thermodynamics ; Energy & Fuels |
WOS Subject | Thermodynamics ; Energy & Fuels |
Funding Organization | National Key R&D Program of China ; 2017 Doctoral International Cooperation Training Program of University of Chinese Academy of Sciences ; Combustion and Harmful Emission Control (CHEC) Research Centre at the Department of Chemical and Biochemical Engineering, Technical University of Denmark ; SinoDanish Center for Education and Research |
WOS ID | WOS:000657660900008 |
Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.ipe.ac.cn/handle/122111/49121 |
Collection | 中国科学院过程工程研究所 |
Corresponding Author | Lin, Weigang |
Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100049, Peoples R China 3.Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark |
First Author Affilication | Center of lonic Liquids and Green Engineering |
Corresponding Author Affilication | Center of lonic Liquids and Green Engineering |
Recommended Citation GB/T 7714 | Chen, Yuan,Lin, Weigang,Wu, Hao,et al. Steam gasification of char derived from penicillin mycelial dreg and lignocellulosic biomass: Influence of P, K and Ca on char reactivity[J]. ENERGY,2021,228:8. |
APA | Chen, Yuan.,Lin, Weigang.,Wu, Hao.,Jensen, Peter Arendt.,Song, Wenli.,...&Li, Songgeng.(2021).Steam gasification of char derived from penicillin mycelial dreg and lignocellulosic biomass: Influence of P, K and Ca on char reactivity.ENERGY,228,8. |
MLA | Chen, Yuan,et al."Steam gasification of char derived from penicillin mycelial dreg and lignocellulosic biomass: Influence of P, K and Ca on char reactivity".ENERGY 228(2021):8. |
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