CAS OpenIR
Solvothermal Synthesis and Conformation Probe of Novel Europium Complex of Bronsted Acidic Ionic Liquid: 1,3-Bis(1-carboxylatoethyl)imidazolium Bromide
Sun, Huimin1; Liu, Mengchen1; Fu, Xiaofang1; Xin, Tingting1; Wang, Yibo1; Wang, Si2; Wang, Jing3; Diao, Yanyan4; Yang, Feifei4; Zhang, Ting1
2021-06-14
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
Pages10
AbstractA novel europium complex [Eu-2(C9N2O4H11)(3)(OH)(2)]Br center dot H2O derived from 1,3-bis (1-carboxylatoethyl)imidazolium bromide ([H(2)bcei]Br, C9N2O4H11=bcei(2-)) was synthesized by solvothermal method. [Eu-2(C9N2O4H11)(3)(OH)(2)]Br center dot H2O possesses 3D structure constructed by Eu-O coordination bonds. In this complex, there are two coordinated environments around Eu3+, and Eu1 and Eu2 are eight- and seven- coordinated chemical sphere, respectively. The hydrogen bonds and electrostatic interactions between H2O molecules, Br- ions and the 3D framework with positive charges enhance its thermostability. So above the temperature of 290 degrees C, the 3D framework of [Eu-2(C9N2O4H11)(3)(OH)(2)]Br center dot H2O begins to decompose. The high-resolution emission spectrum of the complex had been measured, which is consistent with the results of the X-ray crystal structure analysis, and luminescence lifetime for the complex is 0.937 ms.
KeywordMetal organic frameworks Europium complex Solvothermal synthesis Ionic liquid Luminescence probe
DOI10.1002/zaac.202100058
Language英语
WOS KeywordMETAL-ORGANIC FRAMEWORKS ; COORDINATION POLYMERS ; ZWITTERIONS
Funding ProjectNational Natural Science Foundation of China[31972111] ; National Natural Science Foundation of China[21676280] ; Key Research Program of Chinese Academy of Sciences[ZDRW-ZS-2018-1-3]
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
Funding OrganizationNational Natural Science Foundation of China ; Key Research Program of Chinese Academy of Sciences
WOS IDWOS:000661313900001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/49181
Collection中国科学院过程工程研究所
Corresponding AuthorWang, Yibo
Affiliation1.Beijing Technol & Business Univ, Dept Chem, Beijing 100048, Peoples R China
2.Beijing Univ Chem Technol, Anal & Test Ctr, Beijing 100029, Peoples R China
3.Beijing Technol & Business Univ, Sch Food & Hlth, Beijing 100048, Peoples R China
4.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Sun, Huimin,Liu, Mengchen,Fu, Xiaofang,et al. Solvothermal Synthesis and Conformation Probe of Novel Europium Complex of Bronsted Acidic Ionic Liquid: 1,3-Bis(1-carboxylatoethyl)imidazolium Bromide[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2021:10.
APA Sun, Huimin.,Liu, Mengchen.,Fu, Xiaofang.,Xin, Tingting.,Wang, Yibo.,...&Zhang, Ting.(2021).Solvothermal Synthesis and Conformation Probe of Novel Europium Complex of Bronsted Acidic Ionic Liquid: 1,3-Bis(1-carboxylatoethyl)imidazolium Bromide.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,10.
MLA Sun, Huimin,et al."Solvothermal Synthesis and Conformation Probe of Novel Europium Complex of Bronsted Acidic Ionic Liquid: 1,3-Bis(1-carboxylatoethyl)imidazolium Bromide".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2021):10.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Sun, Huimin]'s Articles
[Liu, Mengchen]'s Articles
[Fu, Xiaofang]'s Articles
Baidu academic
Similar articles in Baidu academic
[Sun, Huimin]'s Articles
[Liu, Mengchen]'s Articles
[Fu, Xiaofang]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Sun, Huimin]'s Articles
[Liu, Mengchen]'s Articles
[Fu, Xiaofang]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.