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Effect of ionic liquid on the oxidative esterification from methacrolein to methyl methacrylate
Alternative TitleChem. J. Chin. Univ.-Chin.
Li, GH; Zhang, SJ; Li, ZX; Li, MX; Zhang, XP
2004-06-10
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume25Issue:6Pages:1137-1138
AbstractIonic liquid(IL), [bmim]PF6, was used in the reaction of one-step oxidative esterification from methacrolein to methyl methacrylate. It was found that ionic liquid not only increased the selectivity of methyl methacrylate but also inhibited its polymerization. The selectivity of methyl methacrylate was increased from 45% to 100% with ionic liquid. The experiment results showed that the content of ionic liquid had no effects on the selectivity of methyl methacrylate in a certain range of IL concentration, which indicated that ionic liquid could be used as a potential inhibitor of polymerization.; Ionic liquid(IL), [bmim]PF6, was used in the reaction of one-step oxidative esterification from methacrolein to methyl methacrylate. It was found that ionic liquid not only increased the selectivity of methyl methacrylate but also inhibited its polymerization. The selectivity of methyl methacrylate was increased from 45% to 100% with ionic liquid. The experiment results showed that the content of ionic liquid had no effects on the selectivity of methyl methacrylate in a certain range of IL concentration, which indicated that ionic liquid could be used as a potential inhibitor of polymerization.
KeywordIonic Liquid Methyl Methacrylate Methacrolein Oxidative Esterification Polymerization Inhibitor
SubtypeLetter
WOS HeadingsScience & Technology ; Physical Sciences
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Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000222170400037
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/4921
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China
2.Hebei Normal Univ, Coll Chem, Shijiazhuang 050091, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Li, GH,Zhang, SJ,Li, ZX,et al. Effect of ionic liquid on the oxidative esterification from methacrolein to methyl methacrylate[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(6):1137-1138.
APA Li, GH,Zhang, SJ,Li, ZX,Li, MX,&Zhang, XP.(2004).Effect of ionic liquid on the oxidative esterification from methacrolein to methyl methacrylate.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,25(6),1137-1138.
MLA Li, GH,et al."Effect of ionic liquid on the oxidative esterification from methacrolein to methyl methacrylate".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 25.6(2004):1137-1138.
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离子液体对甲基丙烯醛氧化酯化反应的影响_(86KB) 限制开放CC BY-NC-SAApplication Full Text
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