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| Heteroatoms in graphdiyne for catalytic and energy-related applications | |
| Liu, Baokun1,2; Xu, Lekai3; Zhao, Yasong3; Du, Jiang1,2; Yang, Nailiang3,4; Wang, Dan3,4 | |
| 2021-07-13 | |
| Source Publication | JOURNAL OF MATERIALS CHEMISTRY A
 |
| ISSN | 2050-7488 |
| Pages | 19 |
| Abstract | The recently discovered carbon allotrope GDY possesses rich acetylenic bonds and unique pore structures, prompting GDY as an ideal candidate, tuning its electronic structure by introducing heteroatoms, broadening its usage in catalysis, energy storage and other fields. In this paper, we review different approaches to introduce heteroatoms into GDYs, including monodoping and co-doping, predesigned bottom-up synthesis of GDY, the anchoring of metal atoms into GDYs. Furthermore, we introduce the electronic properties' modification caused by these heteroatoms, including reduced diffusion barrier and adsorption energy, abundant active sites, high reversible capacity and cyclic stability, better rate performance and longer lifespan. Furthermore, the topological molecular structure of GDYs can be tuned through bottom-up synthesis methods with different monomers. GDY has great prospects for inclusion in energy storage devices such as sodium-ion batteries, lithium-ion batteries, lithium/magnesium sulfur batteries, and in electrocatalytic processes such as hydrogen evolution reactions, oxygen reduction reactions, and electrocatalytic nitrogen reduction reactions in important industrial reactions. At the end of this review, challenges and prospects of heteroatoms' introduction into GDY are discussed. |
| DOI | 10.1039/d1ta03634c |
| Language | 英语 |
| WOS Keyword | NITROGEN-DOPED GRAPHDIYNE ; OXYGEN-REDUCTION REACTION ; METAL-FREE CATALYSTS ; LITHIUM-ION ; HIGH-CAPACITY ; INTERFACIAL SYNTHESIS ; CARBON NANOTUBES ; ANODE MATERIAL ; CO OXIDATION ; GRAPHENE |
| WOS Research Area | Chemistry ; Energy & Fuels ; Materials Science |
| WOS Subject | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000680401400001 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/49497 |
| Collection | 中国科学院过程工程研究所 |
| Corresponding Author | Du, Jiang; Yang, Nailiang; Wang, Dan |
| Affiliation | 1.Zhengzhou Univ, Sch Mat Sci & Engn, Henan Prov Ind Technol Res Inst Resources & Mat, Zhengzhou 450001, Peoples R China 2.Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Zhengzhou 450000, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 Beiertiao, Beijing 100190, Peoples R China 4.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Baokun,Xu, Lekai,Zhao, Yasong,et al. Heteroatoms in graphdiyne for catalytic and energy-related applications[J]. JOURNAL OF MATERIALS CHEMISTRY A,2021:19. |
| APA | Liu, Baokun,Xu, Lekai,Zhao, Yasong,Du, Jiang,Yang, Nailiang,&Wang, Dan.(2021).Heteroatoms in graphdiyne for catalytic and energy-related applications.JOURNAL OF MATERIALS CHEMISTRY A,19. |
| MLA | Liu, Baokun,et al."Heteroatoms in graphdiyne for catalytic and energy-related applications".JOURNAL OF MATERIALS CHEMISTRY A (2021):19. |
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