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Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol
Chen, Shengxin1,2; An, Ran2; Li, Yingwei2,3; Zhu, Yuting2,4; Zhu, Xinbao4; Liu, Ruixia2,3; Li, Xingang1; Zhang, Suojiang1,2,3
2021-07-21
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume60Issue:28Pages:10112-10118
AbstractIn recent years, multi-ionic liquids (ILs) mixture systems have been widely noticed and applied in catalysis due to Correction lie their unique properties. In order to establish the quantitative relationship between parameters and catalytic behavior, double salt ILs (DSILs), with different cation (1-ethyl-3-methylimidazolium, choline, tetraethylammonium) but same anion (acetate), are performed in the coupling reaction of propylene oxide (PO) with methanol. In the present work, the DSILs properties like Hammett basicity (H-0), hydrogen bond donor (HBD) ability (alpha), hydrogen bond acceptor (HBA) ability (beta) and dipolarity/polarizability effect (pi*) were considered in the reaction. These control factors were quantitative related to catalytic performance by a modified liner solvent energy relationship (LSER) function that adding a Hammett function correction term. According to the modified LSER, solvents with different parameters were tested to verify its validity and control the reaction. This study demonstrated each parameter could make a different contribution to chemical reaction. It provides a new perspective way for multi-ILs mixture avoiding the intricacies of the parameter relation in ILs catalysis reasonably.
DOI10.1021/acs.iecr.1c01730
Language英语
WOS KeywordSOLVATION ENERGY RELATIONSHIPS ; MIXTURES ; CELLULOSE ; SOLVENT ; VALUES ; SCALE ; BETA
Funding ProjectNational Nature Science Foundation of China[21878315] ; National Key Research and Development Program of China[2017YFA0206803] ; Key Programs of Fujian Institute of Innovation, CAS[FJCXY18020203] ; National Science Fund for Excellent Young Scholars[21722610] ; K. C. Wong Education Foundation[GJTD-2018-04]
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
Funding OrganizationNational Nature Science Foundation of China ; National Key Research and Development Program of China ; Key Programs of Fujian Institute of Innovation, CAS ; National Science Fund for Excellent Young Scholars ; K. C. Wong Education Foundation
WOS IDWOS:000677542700010
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/49554
Collection中国科学院过程工程研究所
Corresponding AuthorLiu, Ruixia; Li, Xingang; Zhang, Suojiang
Affiliation1.Tianjin Univ, Natl Engn Res Ctr Distillat Technol, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
2.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
4.Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Peoples R China
Recommended Citation
GB/T 7714
Chen, Shengxin,An, Ran,Li, Yingwei,et al. Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2021,60(28):10112-10118.
APA Chen, Shengxin.,An, Ran.,Li, Yingwei.,Zhu, Yuting.,Zhu, Xinbao.,...&Zhang, Suojiang.(2021).Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,60(28),10112-10118.
MLA Chen, Shengxin,et al."Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 60.28(2021):10112-10118.
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