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Organic solvent control of inorganic structure: a one-dimensional zirconium phosphate inorganic polymer
Alternative TitleSolid State Ion.
Wang, D; Yu, RB; Xing, XR; Chen, YF; Guoa, ZC; Kumada, N; Kinomura, N; Takano, M
2004-11-30
Source PublicationSOLID STATE IONICS
ISSN0167-2738
Volume175Issue:1-4Pages:751-754
AbstractA novel one-dimensional chain zirconium phosphate inorganic polymer, [NH4](3)[Zr(OH)(2)(PO4)(HPO4)], has been synthesized in a nonaqueous medium, and characterized by means of single-crystal X-ray diffraction, IR, TG-DTA, ICP and CHN elemental analysis. The needle-like crystals of this compound are formed by macroanionic (empirical formula [ZrP2O10H3](3-)) chains of ZrO4(OH)(2) octahedra, PO4 and HPO4 tetrahedra, separated by NH4+ cations. By comparing the synthesis condition and crystal structure of the title compound with those of a new layered [NH4](2)[enH(2)](2)[Zr-3(OH)(6)(PO4)(4)], the structural control effect of organic solvents were further clarified. (C) 2004 Elsevier B.V. All rights reserved.; A novel one-dimensional chain zirconium phosphate inorganic polymer, [NH4](3)[Zr(OH)(2)(PO4)(HPO4)], has been synthesized in a nonaqueous medium, and characterized by means of single-crystal X-ray diffraction, IR, TG-DTA, ICP and CHN elemental analysis. The needle-like crystals of this compound are formed by macroanionic (empirical formula [ZrP2O10H3](3-)) chains of ZrO4(OH)(2) octahedra, PO4 and HPO4 tetrahedra, separated by NH4+ cations. By comparing the synthesis condition and crystal structure of the title compound with those of a new layered [NH4](2)[enH(2)](2)[Zr-3(OH)(6)(PO4)(4)], the structural control effect of organic solvents were further clarified. (C) 2004 Elsevier B.V. All rights reserved.
KeywordNonaqueons Synthesis Crystal Structure Zirconium Phosphate One-dimensional Chain Structure Inorganic Polymer
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.ssi.2003.11.039
URL查看原文
Indexed ByISTP ; SCI
Language英语
WOS KeywordNONAQUEOUS SYNTHESIS ; ALUMINOPHOSPHATE ; LAYER
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Condensed Matter
WOS IDWOS:000225990500153
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/4981
Collection研究所(批量导入)
Affiliation1.Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan
2.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China
3.Univ Sci & Technol Beijing, Dept Chem Phys, Beijing 100083, Peoples R China
4.Yamanashi Univ, Inst Inorgan Synth, Kofu, Yamanashi 4008513, Japan
Recommended Citation
GB/T 7714
Wang, D,Yu, RB,Xing, XR,et al. Organic solvent control of inorganic structure: a one-dimensional zirconium phosphate inorganic polymer[J]. SOLID STATE IONICS,2004,175(1-4):751-754.
APA Wang, D.,Yu, RB.,Xing, XR.,Chen, YF.,Guoa, ZC.,...&Takano, M.(2004).Organic solvent control of inorganic structure: a one-dimensional zirconium phosphate inorganic polymer.SOLID STATE IONICS,175(1-4),751-754.
MLA Wang, D,et al."Organic solvent control of inorganic structure: a one-dimensional zirconium phosphate inorganic polymer".SOLID STATE IONICS 175.1-4(2004):751-754.
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