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Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2
Zhang, Zhibo1; Tong, Jiahuan1; Meng, Xianglei1; Cai, Yingjun1; Ma, Shuangshuang2; Huo, Feng2; Luo, Jianquan3; Xu, Bao-Hua2; Zhang, Suojiang2; Pinelo, Manuel1
2021-08-30
Source PublicationACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN2168-0485
Volume9Issue:34Pages:11503-11511
AbstractNADH is a required cofactor for enzymatic hydrogenation of CO2 to methanol, but the high costs of NADH deter its large-scale application. Photocatalytic reduction of NAD(+) to NADH is a promising solution that utilizes limitless solar energy. The success of photocatalytic reduction of NAD(+) depends on the use of a photosensitizer that must enable efficient electron transfer from the photosensitizer to the catalyst. Among the evaluated photosensitizers, ionic porphyrin (ZnTPyPBr) was found to be the most efficient photosensitizer for in situ NADH regeneration. Compared to the free system (control), methanol concentration was increased sevenfold when a membrane was used as a support to integrate cascade enzymatic reaction and NADH regeneration.
KeywordCO2 reduction NADH regeneration photocatalytic dehydrogenase membrane
DOI10.1021/acssuschemeng.1c03737
Language英语
WOS KeywordARTIFICIAL PHOTOSYNTHESIS SYSTEM ; MULTI-ENZYMATIC CONVERSION ; CARBON-DIOXIDE ; ELECTROCHEMICAL REDUCTION ; COFACTOR REGENERATION ; NADH REGENERATION ; SOLAR-ENERGY ; IMMOBILIZATION ; FILTRATION ; CATALYSIS
Funding ProjectNational Science Foundation of China[U1704251]
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Engineering
WOS SubjectChemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
Funding OrganizationNational Science Foundation of China
WOS IDWOS:000692546300019
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/50124
Collection中国科学院过程工程研究所
Corresponding AuthorZhang, Suojiang; Pinelo, Manuel
Affiliation1.Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark
2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China
3.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Zhibo,Tong, Jiahuan,Meng, Xianglei,et al. Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(34):11503-11511.
APA Zhang, Zhibo.,Tong, Jiahuan.,Meng, Xianglei.,Cai, Yingjun.,Ma, Shuangshuang.,...&Pinelo, Manuel.(2021).Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(34),11503-11511.
MLA Zhang, Zhibo,et al."Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.34(2021):11503-11511.
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